Scanning tunneling microscopy, orbital-mediated tunneling spectroscopy, and ultraviolet photoelectron spectroscopy of metal (II) tetraphenylporphyrins deposited from …

L Scudiero, DE Barlow, U Mazur… - Journal of the American …, 2001 - ACS Publications
Thin films of vapor-deposited Ni (II) and Co (II) complexes of tetraphenylporphyrin (NiTPP
and CoTPP) were studied supported on gold and embedded in Al− Al2O3− MTPP− Pb …

Tunneling-induced luminescence from adsorbed organic molecules with submolecular lateral resolution

G Hoffmann, L Libioulle, R Berndt - Physical Review B, 2002 - APS
Light emission from molecule-covered surfaces in the scanning tunneling microscope has
repeatedly been reported with optical contrast occurring on a molecular scale. The role of …

Dissociation of individual molecules with electrons from the tip of a scanning tunneling microscope

G Dujardin, RE Walkup, P Avouris - Science, 1992 - science.org
The scanning tunneling microscope (STM) can be used to select a particular adsorbed
molecule, probe its electronic structure, dissociate the molecule by using electrons from the …

Controlled manipulation of single atoms and small molecules using the scanning tunnelling microscope

K Morgenstern, N Lorente, KH Rieder - physica status solidi (b), 2013 - Wiley Online Library
This article reviews manipulation of single molecules by scanning tunnelling microscopes, in
particular vertical manipulation, lateral manipulation, and inelastic electron tunnelling (IET) …

Exploring single molecules by scanning probe microscopy: porphyrin and phthalocyanine

T Niu, A Li - The Journal of Physical Chemistry Letters, 2013 - ACS Publications
Utilizing single molecules as the building blocks for electronic devices is one promising
pathway for microelectronic miniaturization. Exploring the molecular conformation and …

How to control single-molecule rotation

GJ Simpson, V García-López, A Daniel Boese… - Nature …, 2019 - nature.com
The orientation of molecules is crucial in many chemical processes. Here, we report how
single dipolar molecules can be oriented with maximum precision using the electric field of a …

Reversible bond formation in a gold-atom–organic-molecule complex as a molecular switch

F Mohn, J Repp, L Gross, G Meyer, MS Dyer… - Physical review …, 2010 - APS
We report on the formation of a metal-molecule complex that can be used as a molecular
switch. Using a cryogenic scanning tunneling microscope, a covalent bond was formed …

Tunnelling junctions with additional degrees of freedom: An extended toolbox of scanning probe microscopy

C Wagner, R Temirov - Progress in surface science, 2015 - Elsevier
Considering studies of molecular adsorption we review recent developments in the field of
scanning probe microscopy and in particular in scanning tunnelling microscopy …

Real-space imaging of molecular structure and chemical bonding by single-molecule inelastic tunneling probe

C Chiang, C Xu, Z Han, W Ho - Science, 2014 - science.org
The arrangement of atoms and bonds in a molecule influences its physical and chemical
properties. The scanning tunneling microscope can provide electronic and vibrational …

Probing molecular excited states by atomic force microscopy

S Fatayer, F Albrecht, I Tavernelli, M Persson, N Moll… - Physical Review Letters, 2021 - APS
By employing single charge injections with an atomic force microscope, we investigated
redox reactions of a molecule on a multilayer insulating film. First, we charged the molecule …