Plasmonic excitation of light emission and absorption by porphyrine molecules in a scanning tunneling microscope

NL Schneider, R Berndt - Physical Review B, 2012 - APS
Light emission from a scanning tunneling microscope is investigated from Ag (111) surfaces
using tips with a clean metallic apex and a molecule-covered shaft. The measurements are …

Imaging porphyrin-based molecules on a gold substrate in ambient conditions

DK Luttrull, J Graham, JA DeRose, D Gust, TA Moore… - Langmuir, 1992 - ACS Publications
Covalently tethering porphyrin-based molecules to an otherwise inert gold substrate allows
them to be imaged in an ambient environment using scanning tunneling microscopy …

Photon emission at molecular resolution induced by a scanning tunneling microscope

R Berndt, R Gaisch, JK Gimzewski, B Reihl… - Science, 1993 - science.org
The tip-surface region of a scanning tunneling microscope (STM) emits light when the
energy of the tunneling electrons is sufficient to excite luminescent processes. These …

STM studies on porphyrins

J Otsuki - Coordination Chemistry Reviews, 2010 - Elsevier
Porphyrins are promising components to be used in molecular electronics due to their rich
electronic/photonic properties. Preparation of supramolecular architectures of porphyrins on …

Controlled Manipulation of Self-Organized Ni (II)− Octaethylporphyrin Molecules Deposited from Solution on HOPG with a Scanning Tunneling Microscope

L Scudiero, KW Hipps - The Journal of Physical Chemistry C, 2007 - ACS Publications
The controlled manipulation of a physisorbed self-assembled monolayer is demonstrated at
room temperature for the first time. Patterns are drawn in a NiOEP monolayer supported on …

Inducing the rotation of a single phenyl ring with tunneling electrons

N Henningsen, KJ Franke, IF Torrente… - The Journal of …, 2007 - ACS Publications
We report on the electron induced intramolecular rotation of a single phenyl ring of an
azobenzene derivative adsorbed on a Au (111) surface using a low-temperature scanning …

Current-induced hydrogen tautomerization and conductance switching of naphthalocyanine molecules

P Liljeroth, J Repp, G Meyer - Science, 2007 - science.org
The bistability in the position of the two hydrogen atoms in the inner cavity of single free-
base naphthalocyanine molecules constitutes a two-level system that was manipulated and …

Tunneling rates in electron transport through double-barrier molecular junctions in a scanning tunneling microscope

GV Nazin, SW Wu, W Ho - Proceedings of the National …, 2005 - National Acad Sciences
The scanning tunneling microscope enables atomic-scale measurements of electron
transport through individual molecules. Copper phthalocyanine and magnesium porphine …

Transfer of Cl ligands between adsorbed iron tetraphenylporphyrin molecules

TG Gopakumar, H Tang, J Morillo… - Journal of the American …, 2012 - ACS Publications
Iron tetraphenylporphyrin chloride (FeTPPCl) adsorbed on a Au (111) substrate is
investigated using low-temperature scanning tunneling microscopy. Cl is controllably …

Single molecule imaging and vibrational spectroscopy with a chemically modified tip of a scanning tunneling microscope

JR Hahn, W Ho - Physical Review Letters, 2001 - APS
The tip of a scanning tunneling microscope can be chemically modified by transferring a
single molecule from the surface. Such a molecule-terminated tip yields enhanced …