Tunneling rates in electron transport through double-barrier molecular junctions in a scanning tunneling microscope

GV Nazin, SW Wu, W Ho - Proceedings of the National …, 2005 - National Acad Sciences
The scanning tunneling microscope enables atomic-scale measurements of electron
transport through individual molecules. Copper phthalocyanine and magnesium porphine …

Transfer of Cl ligands between adsorbed iron tetraphenylporphyrin molecules

TG Gopakumar, H Tang, J Morillo… - Journal of the American …, 2012 - ACS Publications
Iron tetraphenylporphyrin chloride (FeTPPCl) adsorbed on a Au (111) substrate is
investigated using low-temperature scanning tunneling microscopy. Cl is controllably …

Atomic force microscopy reveals bistable configurations of dibenzo [a, h] thianthrene and their interconversion pathway

N Pavliček, B Fleury, M Neu… - Physical review …, 2012 - epub.uni-regensburg.de
We investigated dibenzo [a, h] thianthrene molecules adsorbed on ultrathin layers of NaCl
using a combined low-temperature scanning tunneling and atomic force microscope. Two …

Atomically resolved single-molecule triplet quenching

J Peng, S Sokolov, D Hernangómez-Pérez, F Evers… - Science, 2021 - science.org
The nonequilibrium triplet state of molecules plays an important role in photocatalysis,
organic photovoltaics, and photodynamic therapy. We report the direct measurement of the …

Manipulation of azobenzene molecules on Au (111) using scanning tunneling microscopy

MJ Comstock, J Cho, A Kirakosian, MF Crommie - Physical Review B, 2005 - APS
We have manipulated single azobenzene molecules using several different techniques with
a variable-temperature scanning tunneling microscope (STM). Isolated azobenzene …

Direct observation of photoinduced tautomerization in single molecules at a metal surface

H Böckmann, S Liu, J Mielke, S Gawinkowski… - Nano Letters, 2016 - ACS Publications
Molecular switches are of fundamental importance in nature, and light is an important
stimulus to selectively drive the switching process. However, the local dynamics of a …

Submolecular control, spectroscopy and imaging of bond-selective chemistry in single functionalized molecules

Y Jiang, Q Huan, L Fabris, GC Bazan, W Ho - Nature Chemistry, 2013 - nature.com
One of the key challenges in chemistry is to break and form bonds selectively in complex
organic molecules that possess a range of different functional groups. To do this at the …

A single-molecule chemical reaction studied by high-resolution atomic force microscopy and scanning tunneling microscopy induced light emission

K Kaiser, L Gross, F Schulz - ACS nano, 2019 - ACS Publications
Atomic force microscopy (AFM) as well as scanning tunneling microscopy induced light
emission (STM-LE) are, each on their own, powerful tools used to investigate a large variety …

Imaging bond formation between a gold atom and pentacene on an insulating surface

J Repp, G Meyer, S Paavilainen, FE Olsson, M Persson - Science, 2006 - science.org
A covalent bond between an individual pentacene molecule and a gold atom was formed by
means of single-molecule chemistry inside a scanning tunneling microscope junction. The …

Mapping orbital changes upon electron transfer with tunnelling microscopy on insulators

LL Patera, F Queck, P Scheuerer, J Repp - Nature, 2019 - nature.com
Electron transfer plays a crucial part in many chemical reactions,, including photosynthesis,
combustion and corrosion. But even though redox-state transitions change the electronic …