Modification of molecular conductance by in situ deprotection of thiol-based porphyrin

Q Zhou, A Yamada, Q Feng, A Hoskins… - … Applied Materials & …, 2017 - ACS Publications
Acetylthio-protected free base porphyrins are used to form scanning tunneling microscope-
molecular break junctions. The porphyrin molecules are deprotected in situ, before the self …

Orbital-resolved visualization of single-molecule photocurrent channels

M Imai-Imada, H Imada, K Miwa, Y Tanaka, K Kimura… - Nature, 2022 - nature.com
Given its central role in utilizing light energy, photoinduced electron transfer (PET) from an
excited molecule has been widely studied,,,,–. However, even though microscopic …

Single-molecule investigation of energy dynamics in a coupled plasmon-exciton system

H Imada, K Miwa, M Imai-Imada, S Kawahara… - Physical review …, 2017 - APS
We investigate the near-field interaction between an isolated free-base phthalocyanine
molecule and a plasmon localized in the gap between an NaCl-covered Ag (111) surface …

Nonplanar adsorption and orientational ordering of porphyrin molecules on Au (111)

T Yokoyama, S Yokoyama, T Kamikado… - The Journal of Chemical …, 2001 - pubs.aip.org
Saddle-shaped deformation of planar porphyrin molecules is accomplished by rotations of
four phenyl-based substituents, which results from optimum adsorption onto Au (111) …

Scanning tunneling microscopy manipulation of complex organic molecules on solid surfaces

R Otero, F Rosei, F Besenbacher - Annu. Rev. Phys. Chem., 2006 - annualreviews.org
▪ Abstract Organic molecules adsorbed on solid surfaces display a fascinating variety of new
physical and chemical phenomena ranging from self-assembly and molecular recognition to …

Scanning probe studies of porphyrin assemblies and their supramolecular manipulation at a solid–liquid interface

JAAW Elemans, MC Lensen, JW Gerritsen… - Advanced …, 2003 - Wiley Online Library
Dynamic self‐assembly and metal–ligand coordination processes of porphyrin hexamers on
a solid–liquid interface have been visualized with scanning tunneling microscopy. The …

One-way optoelectronic switching of photochromic molecules on gold

D Dulić, SJ van der Molen, T Kudernac, HT Jonkman… - Physical review …, 2003 - APS
We investigate photochromic molecular switches that are self-assembled on gold. We use
two experimental techniques; namely, the mechanically controllable break-junction …

Manipulation of the electronic structure by reversible dehydrogenation of tetra (p-hydroxyphenyl) porphyrin molecules

L Smykalla, P Shukrynau, C Mende, T Rüffer, H Lang… - Surface science, 2014 - Elsevier
The controlled and reversible interconversion between the free-base and the doubly
dehydrogenated form of a 5, 10, 15, 20-tetra (p-hydroxyphenyl) porphyrin molecule in an …

Atomic and molecular manipulation with the scanning tunneling microscope

JA Stroscio, DM Eigler - Science, 1991 - science.org
The prospect of manipulating matter on the atomic scale has fascinated scientists for
decades. This fascination may be motivated by scientific and technological opportunities, or …

Controlled lateral manipulation of single molecules with the scanning tunneling microscope

G Meyer, B Neu, KH Rieder - Applied Physics A, 1995 - Springer
We report on the first successful lateral manipulation of molecules and controlled formation
of nanostructures with the Scanning Tunneling Microscope (STM) at temperatures above 4 K …