[M III (bpym)(CN) 4]−: a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M= Fe, Cr; bpym= 2, 2′-bypyrimidine)
Two cyano-bridged MIIIMnIII [M= Fe (1) and Cr (2)] ferrimagnetic chains are reported; 2
exhibits metamagnetism with two critical fields of 1250 G and 2.0 T which correspond to the …
exhibits metamagnetism with two critical fields of 1250 G and 2.0 T which correspond to the …
[Fe(bpym)(CN)4]-: A New Building Block for Designing Single-Chain Magnets
We herein present the preparation, crystal structure, magnetic properties, and theoretical
study of new heterobimetallic chains of formula {[FeIII (bpym)(CN4)] 2MII (H2O) 2}⊙ 6H2O …
study of new heterobimetallic chains of formula {[FeIII (bpym)(CN4)] 2MII (H2O) 2}⊙ 6H2O …
Synthesis, crystal structure and magnetic properties of a new cyanide-bridged iron (III)–nickel (II) ferromagnetic chain
V Costa, R Lescouëzec, J Vaissermann, P Herson… - Inorganica Chimica …, 2008 - Elsevier
The reaction of the iron (III) unit fac-[Fe {HB (pz) 3}(CN) 3]−[HB (pz) 3-= hydrotris (1-
pyrazolyl) borate] as the lithium salt (1) with the nickel (II) complex mer-[Ni (dpt)(H2O) …
pyrazolyl) borate] as the lithium salt (1) with the nickel (II) complex mer-[Ni (dpt)(H2O) …
Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged Heterobimetallic Chains Based on [(Tp)Fe(CN)3]-
With the use of the tailored cyanometalate precursor,(Bu4N)[(Tp) Fe (CN) 3](Tp= Tris
(pyrazolyl) hydroborate) as the building block to react with fully solvated CuII, CoII, and NiII …
(pyrazolyl) hydroborate) as the building block to react with fully solvated CuII, CoII, and NiII …
Cyanide-bridged Fe (III)–Co (II) bis double zigzag chains with a slow relaxation of the magnetisation
LM Toma, R Lescouëzec, F Lloret, M Julve… - Chemical …, 2003 - pubs.rsc.org
Reaction of [FeIII (bipy)(CN) 4]− with fully solvated MII cations [M= Co (1) and Mn (2)]
produces the isostructural bis double zigzag chains [[FeIII (bipy)(CN) 4] 2MII (H2O)]· MeCN …
produces the isostructural bis double zigzag chains [[FeIII (bipy)(CN) 4] 2MII (H2O)]· MeCN …
Cyanide-Bridged Fe (III)− Mn (III) Chain with Metamagnetic Properties and Significant Magnetic Anisotropy
S Wang, M Ferbinteanu, M Yamashita - Inorganic chemistry, 2007 - ACS Publications
The assembling of [Mn (5-MeOsalen)(H2O)]+ and [(Tp) Fe (CN) 3]-affords the one-
dimensional zigzag chain [(Tp) Fe (CN) 3Mn (5-MeOsalen)⊙ 2CH3OH] n [1; Tp-= hydrotris …
dimensional zigzag chain [(Tp) Fe (CN) 3Mn (5-MeOsalen)⊙ 2CH3OH] n [1; Tp-= hydrotris …
Cyano-Bridged Bimetallic Assemblies from Hexacyanometalate, [M(CN)6]3- (M = MnIII and FeIII), and [M(N4-macrocycle)]2+ (M = FeIII, NiII and ZnII) Building …
E Colacio, M Ghazi, H Stoeckli-Evans, F Lloret… - Inorganic …, 2001 - ACS Publications
Reactions between [M (N4-macrocycle)] 2+(M= ZnII and NiII; macrocycle ligands are either
CTH= d, l-5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane or cyclam= 1 …
CTH= d, l-5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane or cyclam= 1 …
[Fe III (dmbpy)(CN) 4]−: a new building block for designing single-chain magnets
We herein present the synthesis and magneto-structural study of a new family of
heterobimetallic chains of general formula {[FeIII (dmbpy)(CN) 4] 2MII (H2O) 2} n· pnH2O …
heterobimetallic chains of general formula {[FeIII (dmbpy)(CN) 4] 2MII (H2O) 2} n· pnH2O …
Ferrimagnetic FeIII−MnIII Zigzag Chain Formed by a New mer-Positioned Iron(III) Cyanide Precursor
A new cyanide-bearing molecular precursor, mer-[Fe (pzcq)(CN) 3]-(1), and a zigzag
chain,[Fe (pzcq)(CN) 3][Mn (salen)]⊙ 4H2O (2), were prepared and characterized in terms …
chain,[Fe (pzcq)(CN) 3][Mn (salen)]⊙ 4H2O (2), were prepared and characterized in terms …
Heterotrimetallic Ni 2 Ln 2 Fe 3 chain complexes based on [Fe (1-CH 3 im)(CN) 5] 2−
M Zeng, KQ Hu, CM Liu, HZ Kou - Dalton Transactions, 2021 - pubs.rsc.org
Two phenoxo-and cyanido-bridged one-dimensional complexes NiII2GdIII2FeIII3 (1) and
NiII2DyIII2FeIII3 (2) have been prepared. They are the first pentacyanidoferrite-bridged …
NiII2DyIII2FeIII3 (2) have been prepared. They are the first pentacyanidoferrite-bridged …