Bioinspired metal–polyphenol materials: Self-healing and beyond
A Andersen, Y Chen, H Birkedal - Biomimetics, 2019 - mdpi.com
The blue mussel incorporates the polyphenolic amino acid l-3, 4-dihydroxyphenylalanine
(DOPA) to achieve self-healing, pH-responsiveness, and impressive underwater adhesion …
(DOPA) to achieve self-healing, pH-responsiveness, and impressive underwater adhesion …
Mussel‐inspired materials: self‐healing through coordination chemistry
M Krogsgaard, V Nue, H Birkedal - Chemistry–A European …, 2016 - Wiley Online Library
Improved understanding of the underwater attachment strategy of the blue mussels and
other marine organisms has inspired researchers to find new routes to advanced materials …
other marine organisms has inspired researchers to find new routes to advanced materials …
Biomedical and clinical importance of mussel-inspired polymers and materials
NK Kaushik, N Kaushik, S Pardeshi, JG Sharma… - Marine drugs, 2015 - mdpi.com
The substance secreted by mussels, also known as nature's glue, is a type of liquid protein
that hardens rapidly into a solid water-resistant adhesive material. While in seawater or …
that hardens rapidly into a solid water-resistant adhesive material. While in seawater or …
Metals & polymers in the mix: fine-tuning the mechanical properties & color of self-healing mussel-inspired hydrogels
M Krogsgaard, MR Hansen, H Birkedal - Journal of Materials Chemistry …, 2014 - pubs.rsc.org
Reversible sacrificial bonds play a crucial role in various biological materials where they
serve as load-bearing bonds, facilitating extensibility and/or impart self-healing properties to …
serve as load-bearing bonds, facilitating extensibility and/or impart self-healing properties to …
Healing through histidine: Bioinspired pathways to self-healing polymers via imidazole–metal coordination
Biology offers a valuable inspiration toward the development of self-healing engineering
composites and polymers. In particular, chemical level design principles extracted from …
composites and polymers. In particular, chemical level design principles extracted from …
pH-induced metal-ligand cross-links inspired by mussel yield self-healing polymer networks with near-covalent elastic moduli
N Holten-Andersen, MJ Harrington… - Proceedings of the …, 2011 - National Acad Sciences
Growing evidence supports a critical role of metal-ligand coordination in many attributes of
biological materials including adhesion, self-assembly, toughness, and hardness without …
biological materials including adhesion, self-assembly, toughness, and hardness without …
Metal–ligand interactions and salt bridges as sacrificial bonds in mussel byssus-derived materials
F Byette, A Laventure, I Marcotte, C Pellerin - Biomacromolecules, 2016 - ACS Publications
The byssus that anchors mussels to solid surfaces is a protein-based material combining
strength and toughness as well as a self-healing ability. These exceptional mechanical …
strength and toughness as well as a self-healing ability. These exceptional mechanical …
Versatile tuning of supramolecular hydrogels through metal complexation of oxidation-resistant catechol-inspired ligands
The mussel byssal cuticle employs DOPA–Fe3+ complexation to provide strong, yet
reversible crosslinking. Synthetic constructs employing this design motif based on catechol …
reversible crosslinking. Synthetic constructs employing this design motif based on catechol …
Mussel byssus structure‐function and fabrication as inspiration for biotechnological production of advanced materials
Biotechnology offers an exciting avenue toward the sustainable production of high
performance proteinaceous polymeric materials. In particular, the mussel byssus—a high …
performance proteinaceous polymeric materials. In particular, the mussel byssus—a high …
pH‐based regulation of hydrogel mechanical properties through mussel‐inspired chemistry and processing
DG Barrett, DE Fullenkamp, L He… - Advanced functional …, 2013 - Wiley Online Library
The mechanical holdfast of the mussel, the byssus, is processed at acidic pH yet functions at
alkaline pH. Byssi are enriched in Fe3+ and catechol‐containing proteins, species with …
alkaline pH. Byssi are enriched in Fe3+ and catechol‐containing proteins, species with …