Bioinspired metal–polyphenol materials: Self-healing and beyond

A Andersen, Y Chen, H Birkedal - Biomimetics, 2019 - mdpi.com
The blue mussel incorporates the polyphenolic amino acid l-3, 4-dihydroxyphenylalanine
(DOPA) to achieve self-healing, pH-responsiveness, and impressive underwater adhesion …

Mussel‐inspired materials: self‐healing through coordination chemistry

M Krogsgaard, V Nue, H Birkedal - Chemistry–A European …, 2016 - Wiley Online Library
Improved understanding of the underwater attachment strategy of the blue mussels and
other marine organisms has inspired researchers to find new routes to advanced materials …

Biomedical and clinical importance of mussel-inspired polymers and materials

NK Kaushik, N Kaushik, S Pardeshi, JG Sharma… - Marine drugs, 2015 - mdpi.com
The substance secreted by mussels, also known as nature's glue, is a type of liquid protein
that hardens rapidly into a solid water-resistant adhesive material. While in seawater or …

Metals & polymers in the mix: fine-tuning the mechanical properties & color of self-healing mussel-inspired hydrogels

M Krogsgaard, MR Hansen, H Birkedal - Journal of Materials Chemistry …, 2014 - pubs.rsc.org
Reversible sacrificial bonds play a crucial role in various biological materials where they
serve as load-bearing bonds, facilitating extensibility and/or impart self-healing properties to …

Healing through histidine: Bioinspired pathways to self-healing polymers via imidazole–metal coordination

S Zechel, MD Hager, T Priemel, MJ Harrington - Biomimetics, 2019 - mdpi.com
Biology offers a valuable inspiration toward the development of self-healing engineering
composites and polymers. In particular, chemical level design principles extracted from …

pH-induced metal-ligand cross-links inspired by mussel yield self-healing polymer networks with near-covalent elastic moduli

N Holten-Andersen, MJ Harrington… - Proceedings of the …, 2011 - National Acad Sciences
Growing evidence supports a critical role of metal-ligand coordination in many attributes of
biological materials including adhesion, self-assembly, toughness, and hardness without …

Metal–ligand interactions and salt bridges as sacrificial bonds in mussel byssus-derived materials

F Byette, A Laventure, I Marcotte, C Pellerin - Biomacromolecules, 2016 - ACS Publications
The byssus that anchors mussels to solid surfaces is a protein-based material combining
strength and toughness as well as a self-healing ability. These exceptional mechanical …

Versatile tuning of supramolecular hydrogels through metal complexation of oxidation-resistant catechol-inspired ligands

MS Menyo, CJ Hawker, JH Waite - Soft Matter, 2013 - pubs.rsc.org
The mussel byssal cuticle employs DOPA–Fe3+ complexation to provide strong, yet
reversible crosslinking. Synthetic constructs employing this design motif based on catechol …

Mussel byssus structure‐function and fabrication as inspiration for biotechnological production of advanced materials

MJ Harrington, F Jehle, T Priemel - Biotechnology journal, 2018 - Wiley Online Library
Biotechnology offers an exciting avenue toward the sustainable production of high
performance proteinaceous polymeric materials. In particular, the mussel byssus—a high …

pH‐based regulation of hydrogel mechanical properties through mussel‐inspired chemistry and processing

DG Barrett, DE Fullenkamp, L He… - Advanced functional …, 2013 - Wiley Online Library
The mechanical holdfast of the mussel, the byssus, is processed at acidic pH yet functions at
alkaline pH. Byssi are enriched in Fe3+ and catechol‐containing proteins, species with …