Visualization of Heterogeneous Oxygen Storage Behavior in Platinum‐Supported Cerium‐Zirconium Oxide Three‐Way Catalyst Particles by Hard X‐ray Spectro …

M Hirose, N Ishiguro, K Shimomura… - Angewandte Chemie …, 2018 - Wiley Online Library
The cerium density and valence in micrometer‐size platinum‐supported cerium–zirconium
oxide Pt/Ce2Zr2Ox (x= 7–8) three‐way catalyst particles were successfully mapped by hard …

Imaging of Oxygen Diffusion in Individual Platinum/Ce2Zr2Ox Catalyst Particles During Oxygen Storage and Release

H Matsui, N Ishiguro, K Enomoto… - Angewandte Chemie …, 2016 - Wiley Online Library
The spatial distribution of Ce3+ and Ce4+ in each particle of Ce2Zr2Ox in a three‐way
conversion catalyst system was successfully imaged during an oxygen storage/release cycle …

Visualization of the Heterogeneity of Cerium Oxidation States in Single Pt/Ce2Zr2Ox Catalyst Particles by Nano‐XAFS

N Ishiguro, T Uruga, O Sekizawa, T Tsuji… - …, 2014 - Wiley Online Library
The cerium oxidation states in single catalyst particles of Pt/Ce2Zr2Ox (x= 7 to 8) were
investigated by spatially resolved nano X‐ray absorption fine structure (nano‐XAFS) using …

Oxygen-diffusion-driven oxidation behavior and tracking areas visualized by X-ray spectro-ptychography with unsupervised learning

M Hirose, N Ishiguro, K Shimomura… - Communications …, 2019 - nature.com
Oxygen storage and release with oxygen diffusion in the bulk of the cerium–zirconium solid
solution oxide Ce2Zr2O x (x= 7–8), which possesses an atomically ordered arrangement of …

[PDF][PDF] Observing oxygen storage and release at work during cycling redox conditions: synergies between noble metal and oxide promoter

MA Newton, M Di Michiel, A Kubacka… - Angewandte Chemie …, 2012 - academia.edu
The ability of many materials to store and release gases lies at the core of a range of
economically and environmentally important technologies.[1–6] To this end much research …

Time-resolved X-ray powder diffraction on a three-way catalyst at the GILDA beamline

A Martorana, G Deganello, A Longo… - Journal of …, 2003 - journals.iucr.org
Time-resolved X-ray diffraction experiments carried out at the beamline BM08-GILDA of
ESRF allowed a study of the structural modifications taking place in a Pt/ceria–zirconia …

Investigating the Dynamics of Pt/CeO2 Catalysts at the Powder Agglomerate Scale by Combining In Situ Hyperspectral Raman Imaging and SEM‐EDX Analysis

C Molinet‐Chinaglia, L Piccolo, S Loridant - ChemCatChem, 2023 - Wiley Online Library
Abstract The dynamics of Pt/CeO2 catalysts is a hot topic since its knowledge can be used to
(re) generate more active sites for redox reactions, even at low temperature (< 500° C) …

Detection of ambient oxidation of ultrasmall supported platinum nanoparticles with benchtop powder X-ray diffraction

R Banerjee, Q Liu, JMM Tengco, JR Regalbuto - Catalysis Letters, 2017 - Springer
The ability of a benchtop powder X-ray diffractometer with a solid state detector to observe
the ambient oxidation of ultrasmall (sub 2.5 nm) Pt particles, previously seen only with …

[PDF][PDF] A cell design for correlative hard X-ray nanoprobe and electron microscopy studies of catalysts under in situ conditions

JE Parker, M Gomez-Gonzalez… - Journal of …, 2022 - journals.iucr.org
To improve the understanding of catalysts, and ultimately the ability to design better
materials, it is crucial to study them during their catalytic active states. Using in situ or …

Origin and Dynamics of Oxygen Storage/Release in a Pt/Ordered CeO2–ZrO2 Catalyst Studied by Time‐Resolved XAFS Analysis

T Yamamoto, A Suzuki, Y Nagai… - Angewandte Chemie …, 2007 - Wiley Online Library
CeO2 and cerium-based materials can store oxygen under excess-oxygen conditions and
release it under oxygen-deficient conditions, and owing to the high oxygen storage/release …