Direct and catalyst-free ester metathesis reaction for covalent adaptable networks
S Yang, W Liu, J Guo, Z Yang, Z Qiao… - Journal of the …, 2023 - ACS Publications
Thermosetting polymers possess excellent environmental resistance and mechanical
properties but cannot be reprocessed due to their covalently cross-linked structures …
properties but cannot be reprocessed due to their covalently cross-linked structures …
Olefin metathesis-based chemically recyclable polymers enabled by fused-ring monomers
A promising solution to address the challenges in plastics sustainability is to replace current
polymers with chemically recyclable ones that can depolymerize into their constituent …
polymers with chemically recyclable ones that can depolymerize into their constituent …
Dynamic remodeling of covalent networks via ring-opening metathesis polymerization
Reversible transformations in bulk polymers offer numerous possibilities for materials
remodeling and reprocessing. While reversible systems based on dynamic covalent …
remodeling and reprocessing. While reversible systems based on dynamic covalent …
Making insoluble polymer networks malleable via olefin metathesis
YX Lu, F Tournilhac, L Leibler… - Journal of the American …, 2012 - ACS Publications
Covalently cross-linked polymers have many technological applications for their excellent
properties, but they suffer from the lack of processability and adaptive properties. We report …
properties, but they suffer from the lack of processability and adaptive properties. We report …
Degradable polymers via olefin metathesis polymerization
The development of degradable polymers has commanded significant attention over the
past half century. Approaches have predominantly relied on ring-opening polymerization of …
past half century. Approaches have predominantly relied on ring-opening polymerization of …
Internal catalysis in covalent adaptable networks: phthalate monoester transesterification as a versatile dynamic cross-linking chemistry
M Delahaye, JM Winne, FE Du Prez - Journal of the American …, 2019 - ACS Publications
Covalent adaptable networks (CANs) often make use of highly active external catalysts to
provide swift exchange of the dynamic chemical bonds. Alternatively, milder species can act …
provide swift exchange of the dynamic chemical bonds. Alternatively, milder species can act …
Modification of proteins using olefin metathesis
MS Messina, HD Maynard - Materials chemistry frontiers, 2020 - pubs.rsc.org
Olefin metathesis has revolutionized synthetic approaches to carbon–carbon bond
formation. With a rich history beginning in industrial settings through its advancement in …
formation. With a rich history beginning in industrial settings through its advancement in …
Mechanically robust and reprocessable imine exchange networks from modular polyester pre-polymers
Covalent adaptable networks (CANs) containing reversible cross-links impart recyclability to
thermoset materials without sacrificing their desirable properties (eg high tensile strength …
thermoset materials without sacrificing their desirable properties (eg high tensile strength …
Sequence-controlled copolymers prepared via entropy-driven ring-opening metathesis polymerization
RM Weiss, AL Short, TY Meyer - ACS Macro Letters, 2015 - ACS Publications
A new general synthetic approach to sequenced macromolecules was developed and
applied to the synthesis of polymers comprising lactic acid (L), glycolic acid (G), and ε …
applied to the synthesis of polymers comprising lactic acid (L), glycolic acid (G), and ε …
Degradable polyacetals/ketals from alternating ring-opening metathesis polymerization
We report the synthesis of degradable polyacetals and polyketals with controlled molecular
weights and low dispersities using alternating ring-opening metathesis polymerization …
weights and low dispersities using alternating ring-opening metathesis polymerization …