A calculation of the energies of the dipolar and quadrupolar electric fields of a 1, 2-
disubstituted ethane and their dependence on the dielectric constant of the medium gave …

Proton and fluorine magnetic resonance spectra have been observed in 12 liquid
polysubstituted ethanes over temperature ranges of 250° to 450° K. In each of these …

The free energy difference between the two chair conformations of trans-1, 2-dichloro-and-1,
2-dibromo-cyclohexane (II) and trans-1, 4-dichloro-and-1, 4-dibromo-cyclohexane (III) has …

The NMR spectra of several 1, 2‐disubstituted propanes, particularly 1, 2‐dichloropropane
and 1, 2‐dibromopropane, are examined in detail in various media. A range of vicinal J …

The 90.5-MHz 13C NMR spectrum of 2, 3-dimethylbutane at-180 C shows that thegauche
and antirotational iso-mers are present in the statisticalratio of 2: 1. Line shape analysis of …

The conformations of benzyl alcohol, the ortho and para nitro and methoxy derivatives and
benzyl methyl ether have been investigated by NMR in CCL4 and DMSO solutions. The 3J …

The effect of aromatic solvents such as pyridine, collidine, andbenzene upon the chemical
shift ofprotons in systems possessing internal hindered rotation has been studied. It was …

CONFORMATIONAL analysis of cyclohexane derivatives has only become fully established
since 1945, l but one of the basic tenets, the rapid interconversion among various …

The stereodynamical processes in phenyl 2, 4, 6-triisopropylphenyl ketone and the
analogues C= S, C= NH, and C= CPh2 have been investigated by NMR. In all these …

The rate of conformational isomerization of cyclohexane has been measured over the
temperature range—75.0 to—47.0° by observation of the NMR spectrum of C6HD11, which …