Visible light-mediated intermolecular crossed [2+ 2] cycloadditions using a MOF-supported copper triplet photosensitizer
Abstract The photochemical [2+ 2] cycloaddition of styrenes provides a frequently used route
for the synthesis of multi-substituted cyclobutanes. Despite the extensive studies in noble …
for the synthesis of multi-substituted cyclobutanes. Despite the extensive studies in noble …
Intermolecular 2+ 2 imine-olefin photocycloadditions enabled by Cu (I)-alkene MLCT
DM Flores, ML Neville, VA Schmidt - Nature communications, 2022 - nature.com
Abstract 2+ 2 Photocycloadditions are idealized, convergent construction approaches of 4-
membered heterocyclic rings, including azetidines. However, methods of direct excitation …
membered heterocyclic rings, including azetidines. However, methods of direct excitation …
Cage-confined photocatalysis for wide-scope unusually selective [2+ 2] cycloaddition through visible-light triplet sensitization
JS Wang, K Wu, C Yin, K Li, Y Huang, J Ruan… - Nature …, 2020 - nature.com
Abstract Light-induced [2+ 2] cycloaddition is the most straightforward way to generate
cyclobutanes, which are core structures of many natural products, drugs and bioactive …
cyclobutanes, which are core structures of many natural products, drugs and bioactive …
Intermolecular 2+ 2 Carbonyl–Olefin Photocycloadditions Enabled by Cu (I)–Norbornene MLCT
DM Flores, VA Schmidt - Journal of the American Chemical …, 2019 - ACS Publications
Photocycloadditions are often typified by the oxetane-forming Paternò–Büchi reaction.
However, the mechanistic constraints of carbonyl excitation and olefin interception have …
However, the mechanistic constraints of carbonyl excitation and olefin interception have …
[2+ 2] Cycloaddition of 1, 3‐dienes by visible light photocatalysis
Photocycloadditions of 1, 3‐dienes represent a powerful yet synthetically underutilized class
of reactions. We report that visible light absorbing transition metal complexes enable the [2+ …
of reactions. We report that visible light absorbing transition metal complexes enable the [2+ …
Photocatalytic regioselective and stereoselective [2+ 2] cycloaddition of styrene derivatives using a heterogeneous organic photocatalyst
Photocatalytic [2+ 2] cycloaddition is a useful tool for the synthesis of cyclobutane
derivatives, which contributes a large part to natural compound production. Usually, the [2+ …
derivatives, which contributes a large part to natural compound production. Usually, the [2+ …
Aggregation-enabled intermolecular photo [2+ 2] cycloaddition of aryl terminal olefins by visible-light catalysis
Photo [2+ 2] cycloaddition of olefins is a sought-after tool for making cyclobutanes, which are
the building blocks for a wide range of biologically active molecules and natural products …
the building blocks for a wide range of biologically active molecules and natural products …
Tailoring a decatungstate-incorporated metal-organic framework for light-driven [3+ 2] cyclization of phenols with olefins
T Zhang, J Jiao, K Guo, L Zhang, J Xu, Q Han - Journal of Catalysis, 2024 - Elsevier
Abstract Photocatalytic oxidative [3+ 2] cycloaddition of phenol-olefin is an economy and
green strategy to synthesize 2, 3-Dihydrobenzofurans (2, 3-DHBs) compared with the …
green strategy to synthesize 2, 3-Dihydrobenzofurans (2, 3-DHBs) compared with the …
Visible light-gated cobalt catalysis for a spatially and temporally resolved [2+ 2+ 2] cycloaddition
KE Ruhl, T Rovis - Journal of the American Chemical Society, 2016 - ACS Publications
The ability to exert spatial and temporal control over a transition-metal catalyst offers diverse
opportunities for the fabrication of functional materials. Using an external stimulus such as …
opportunities for the fabrication of functional materials. Using an external stimulus such as …
Mechanistic and Kinetic Insights into Intermolecular [2+ 2] Photocycloadditions
Polypyridyl metal complexes of ruthenium (II) have emerged as efficient single electron
transfer (SET) reagents for photocatalytic reactions, allowing a variety of organic …
transfer (SET) reagents for photocatalytic reactions, allowing a variety of organic …