Identification of the electronic and structural dynamics of catalytic centers in single-Fe-atom material
The lack of model single-atom catalysts (SACs) and atomic-resolution operando
spectroscopic techniques greatly limits our comprehension of the nature of catalysis. Herein …
spectroscopic techniques greatly limits our comprehension of the nature of catalysis. Herein …
Identification of the evolving dynamics of coordination-unsaturated iron atomic active sites under reaction conditions
W Zhou, H Su, Y Li, M Liu, H Zhang, X Zhang… - ACS Energy …, 2021 - ACS Publications
Understanding the nature of the catalytic active center and its evolving dynamics under
operating conditions is critical for the development of efficient and highly selective catalysts …
operating conditions is critical for the development of efficient and highly selective catalysts …
Markedly enhanced oxygen reduction activity of single-atom Fe catalysts via integration with Fe nanoclusters
Single-atom catalysts (SACs) have emerged as one of the most promising alternatives to
noble metal-based catalysts for highly efficient oxygen reduction reaction (ORR). While …
noble metal-based catalysts for highly efficient oxygen reduction reaction (ORR). While …
Electronically and geometrically modified single‐atom Fe sites by adjacent Fe nanoparticles for enhanced oxygen reduction
Fe–N–C materials exhibit excellent activity and stability for oxygen reduction reaction (ORR),
as one of the most promising candidates to replace commercial Pt/C catalysts. However, it is …
as one of the most promising candidates to replace commercial Pt/C catalysts. However, it is …
Unified ORR Mechanism Criteria via Charge− Spin− Coordination of Fe Functional Units
K Song, B Yang, X Zou, W Zhang… - Energy & Environmental …, 2023 - pubs.rsc.org
For oxygen reduction reaction (ORR) consisting of complex multi-electron and proton-
coupled elementary steps, it has been always a core issue to address controlling the …
coupled elementary steps, it has been always a core issue to address controlling the …
Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction
The development of efficient non-platinum group metal (non-PGM) catalysts for oxygen
reduction reaction (ORR) is of paramount importance for clean and sustainable energy …
reduction reaction (ORR) is of paramount importance for clean and sustainable energy …
Self-adjusting activity induced by intrinsic reaction intermediate in Fe–N–C single-atom catalysts
Fe–N–C single-atom catalysts (SACs) exhibit high activity for oxygen reduction reaction
(ORR). However, it remains controversial how the active center mediates catalysis, and the …
(ORR). However, it remains controversial how the active center mediates catalysis, and the …
Unveiling the high-activity origin of single-atom iron catalysts for oxygen reduction reaction
L Yang, D Cheng, H Xu, X Zeng… - Proceedings of the …, 2018 - National Acad Sciences
It is still a grand challenge to develop a highly efficient nonprecious-metal electrocatalyst to
replace the Pt-based catalysts for oxygen reduction reaction (ORR). Here, we propose a …
replace the Pt-based catalysts for oxygen reduction reaction (ORR). Here, we propose a …
Boosting oxygen reduction of single iron active sites via geometric and electronic engineering: nitrogen and phosphorus dual coordination
Atomically dispersed transition metal active sites have emerged as one of the most important
fields of study because they display promising performance in catalysis and have the …
fields of study because they display promising performance in catalysis and have the …
Inter-site structural heterogeneity induction of single atom Fe catalysts for robust oxygen reduction
P Zhang, HC Chen, H Zhu, K Chen, T Li, Y Zhao… - Nature …, 2024 - nature.com
Metal-nitrogen-carbon catalysts with hierarchically dispersed porosity are deemed as
efficient geometry for oxygen reduction reaction (ORR). However, catalytic performance …
efficient geometry for oxygen reduction reaction (ORR). However, catalytic performance …