Nonlinear dynamics of capacitive charging and desalination by porous electrodes
PM Biesheuvel, MZ Bazant - Physical Review E—Statistical, Nonlinear, and …, 2010 - APS
The rapid and efficient exchange of ions between porous electrodes and aqueous solutions
is important in many applications, such as electrical energy storage by supercapacitors …
is important in many applications, such as electrical energy storage by supercapacitors …
Time-dependent ion selectivity in capacitive charging of porous electrodes
In a combined experimental and theoretical study, we show that capacitive charging of
porous electrodes in multicomponent electrolytes may lead to the phenomenon of time …
porous electrodes in multicomponent electrolytes may lead to the phenomenon of time …
Two-dimensional porous electrode model for capacitive deionization
A Hemmatifar, M Stadermann… - The Journal of Physical …, 2015 - ACS Publications
Ion transport in porous conductive materials is of great importance in a variety of
electrochemical systems including batteries and supercapacitors. We here analyze the …
electrochemical systems including batteries and supercapacitors. We here analyze the …
Charge efficiency: a functional tool to probe the double-layer structure inside of porous electrodes and application in the modeling of capacitive deionization
R Zhao, PM Biesheuvel, H Miedema… - The Journal of …, 2010 - ACS Publications
Porous electrodes are important in many physical− chemical processes including capacitive
deionization (CDI), a desalination technology where ions are adsorbed from solution into the …
deionization (CDI), a desalination technology where ions are adsorbed from solution into the …
Diffuse charge and Faradaic reactions in porous electrodes
Porous electrodes instead of flat electrodes are widely used in electrochemical systems to
boost storage capacities for ions and electrons, to improve the transport of mass and charge …
boost storage capacities for ions and electrons, to improve the transport of mass and charge …
Analysis of electrolyte transport through charged nanopores
We revisit the classical problem of flow of electrolyte solutions through charged capillary
nanopores or nanotubes as described by the capillary pore model (also called “space …
nanopores or nanotubes as described by the capillary pore model (also called “space …
Theory of water desalination with intercalation materials
We present a porous electrode theory for capacitive deionization with electrodes containing
nanoparticles that consist of a redox-active intercalation material. A geometry of a …
nanoparticles that consist of a redox-active intercalation material. A geometry of a …
Electrochemistry and capacitive charging of porous electrodes in asymmetric multicomponent electrolytes
We present porous electrode theory for the general situation of electrolytes containing
mixtures of mobile ions of arbitrary valencies and diffusion coefficients (mobilities). We focus …
mixtures of mobile ions of arbitrary valencies and diffusion coefficients (mobilities). We focus …
[HTML][HTML] Theory of water desalination by porous electrodes with immobile chemical charge
In capacitive deionization (CDI), water is desalinated by storing ions in electrical double
layers (EDLs) within the micropores of charged porous carbon electrodes. Recent …
layers (EDLs) within the micropores of charged porous carbon electrodes. Recent …
Strongly nonlinear dynamics of electrolytes in large ac voltages
We study the response of a model microelectrochemical cell to a large ac voltage of
frequency comparable to the inverse cell relaxation time. To bring out the basic physics, we …
frequency comparable to the inverse cell relaxation time. To bring out the basic physics, we …
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