Design criteria for dysprosium (III) single-molecule magnets (SMMs) with large thermal
energy barriers to magnetic reversal have been established and proven, and the challenge …

The effect of electron-withdrawing ligands on the energy barriers of Single-Molecule
Magnets (SMMs) is investigated. By introducing highly electron-withdrawing atoms on …

Efficient modulation of single‐molecule magnet (SMM) behavior was realized by deliberate
structural modification of the Dy2 cores of [Dy2 (a′ povh) 2 (OAc) 2 (DMF) 2](1) and …

A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …

Organometallic molecules based on [Dy (CpR) 2]+ cations (where CpR is a substituted
cyclopentadienyl anion) have emerged as clear front-runners in the search for high …

Following the discovery in the early 1990s that individual molecules can exhibit slow
relaxation of magnetization and magnetic hysteresis,[1] studies of single-molecule magnets …

Design and synthesis of air-stable and easily tailored high-performance single-molecule
magnets (SMMs) are of great significance toward the implementation of SMMs in molecular …

We report a monometallic dysprosium complex,[Dy (OtBu) 2 (py) 5][BPh4](5), that shows the
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …

Conspectus The discovery of materials capable of storing magnetic information at the level
of single molecules and even single atoms has fueled renewed interest in the slow magnetic …

We discuss a cost-effective approach to understand magnetic relaxation in the new
generation of rare-earth single-molecule magnets. It combines ab initio calculations of the …