Thermodynamic parameters for the solvation of monatomic ions in water

WR Fawcett - The Journal of Physical Chemistry B, 1999 - ACS Publications
The estimation of solvation parameters for monatomic ions is reviewed and new values for
the Gibbs energy, enthalpy, and entropy of solvation are given on the basis of the most …

Gibbs energy of solvation of organic ions in aqueous and dimethyl sulfoxide solutions

JR Pliego Jr, JM Riveros - Physical Chemistry Chemical Physics, 2002 - pubs.rsc.org
The Gibbs energy of solvation of several ions in water and dimethyl sulfoxide (DMSO)
solutions was obtained through the use of thermodynamic equations relating ΔGsolv* of the …

Application of the mean spherical approximation to describe the Gibbs solvation energies of monovalent monoatomic ions in polar solvents

L Blum, WR Fawcett - The Journal of Physical Chemistry, 1992 - ACS Publications
The mean spherical approximation for the ion-dipolemixture is used to study the solvation
energies of monovalent monoatomic ions in polar solvents. From the structure of the …

Thermodynamics of ion solvation in water and propylene carbonate

M Salomon - The Journal of Physical Chemistry, 1970 - ACS Publications
The energetics of single-ion solvation in water and propylene carbonate are evaluated on
the basis of an elec-trostatic model. Single-ion free energies of solvation are obtained by …

Solvation enthalpies of various ions in water and heavy water

CV Krishnan, HL Friedman - The Journal of Physical Chemistry, 1970 - ACS Publications
New data are reported for enthalpies of transfer of many electrolytes to D20 from H20 at 25.
Single ion enthalpies of transfer, based on the convention that the enthalpy of transfer is the …

The thermodynamics of solvation of ions. Part 1.—The heat capacity of hydration at 298.15 K

MH Abraham, Y Marcus - Journal of the Chemical Society, Faraday …, 1986 - pubs.rsc.org
Values of the standard partial molar heat capacities of aqueous electrolytes have been
critically selected from the literature and have been divided into ionic contributions using the …

New values for the absolute solvation free energy of univalent ions in aqueous solution

JR Pliego Jr, JM Riveros - Chemical Physics Letters, 2000 - Elsevier
The absolute solvation free energy of 30 univalent ions, mainly organic species, has been
calculated from experimental and theoretical data on proton affinities, aqueous acidity …

Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K

Y Marcus - Journal of the Chemical Society, Faraday Transactions, 1991 - pubs.rsc.org
The standard molar Gibbs free energies of hydration, ΔhydG°, of 109 (mainly inorganic) ions
ranging in their charges from–3 to+ 4 have been compiled and interpreted in terms of a …

Ionic solvation in methanol+ water mixtures. Free energies of transfer from water

CF Wells - Journal of the Chemical Society, Faraday Transactions …, 1973 - pubs.rsc.org
The free energy of transfer ΔG° t (H+) of the solvated proton from water to methanol+ water
mixtures up to 50% w/w methanol is considered as the sum of two processes, the transfer of …

Preferential Solvation of Single Ions: The PH4ASPH4B Assumption for Single Ion Thermodynamics in Mixed Dimethylsulfoxide‐Water Solvents

JI Kim, EA Gomaa - Bulletin des Sociétés Chimiques Belges, 1981 - Wiley Online Library
The paper presents a study of the Ph4AsPh4B assumption as for verification of its plausibility
for the determination of thermodynamic quantities of single ions in mixed dimethylsulfoxide …