A novel DCC reaction between aromatic aldehydes or ketones and H-phosphonates has
been developed for the synthesis of p-formyl or p-acylphenylphosphonates. The synthetic …

A novel and convenient approach for the synthesis of vinyl phosphonates has been
developed, utilizing an aromatic aza-Claisen rearrangement of β, γ-unsaturated α …

A mild method for selective synthesis of o-acylbenzylphosphonates has been developed by
the reactions of arynes with β-ketophosphonates. In the presence of CsF and THF, the …

A novel approach to H-phosphonates from hypophosphorous acid using a transfer
hydrogenation process was developed. This method is atom-economical, environmentally …

Stereoselective One-Pot Synthesis of Functionalised Phosphonates by Three-Component
Reaction between Trimethylphosphite, Dialkyl Page 1 PAPER: 06/4297 Stereoselective one-pot …

We have developed a new, efficient method for the synthesis of benzylphosphonate and
benzylphosphonothioate diesters via a palladium (0)-catalyzed cross-coupling reaction …

Three-component coupling of acylphosphonates and two carbonyl compounds leading to β-
hydroxyphosphonates has been achieved with low-valent samariums. Thus …

An efficient method for the synthesis of organophosphonates through palladium-catalyzed
coupling of α-diazo phosphonates with benzyl or allyl halides has been developed …

Direct Synthesis of Amino-substituted Aromatic Phosphonates via Palladium-catalyzed Coupling
of Aromatic Mono- and Dibromides w Page 1 Direct Synthesis of Amino-substituted Aromatic …

抄録 In recent years there has been a broadly expanding interest in the synthesis of α-
heteroatom-substituted phosphonates such as those bearing amino, hydroxy, and fluoro …