Identification of multiple diffusion rates in mixed solvent anion exchange membranes using high resolution MAS NMR

JE Jenkins, MR Hibbs, TM Alam - Acs Macro Letters, 2012 - ACS Publications
High resolution magic angle spinning (HRMAS) 1H NMR in combination with 2D exchange
NOESY and pulsed field gradient (PFG) NMR diffusion experiments have been used to …

Characterization of heterogeneous solvent diffusion environments in anion exchange membranes

TM Alam, MR Hibbs - Macromolecules, 2014 - ACS Publications
1H high resolution magic angle spinning (HRMAS) NMR spectroscopy was used to
characterize the solvent environments in a series of poly (phenylene)-and poly (phenylene …

Quantitative 1H NMR Analysis of Chemical Stabilities in Anion-Exchange Membranes

SA Nuñez, MA Hickner - Acs Macro Letters, 2013 - ACS Publications
We compared the alkaline stability of three classes of anion exchange membranes that are
leading candidates for applications in platinum-free fuel cells. A methodology is presented …

Multiscale tortuous diffusion in anion and cation exchange membranes

LM Thieu, L Zhu, AG Korovich, MA Hickner… - …, 2018 - ACS Publications
A fundamental understanding of water transport and morphology is critical for improving
ionic conductivity in polymer membranes. In a series of random copolymer anion exchange …

Tracer-Desorption 1H NMR Measurement of Diffusion Coefficients in Polyphosphazene Ion-Exchange Membranes

R Carter, RF Evilia, PN Pintauro - The Journal of Physical …, 2001 - ACS Publications
The growth of an NMR signal due to diffusion of solute out of a thin membrane has been
investigated for the measurement of diffusion rates under conditions that are not suitable for …

Unraveling water and salt transport in polyamide with nuclear magnetic resonance spectroscopy

M Abbaszadeh, M Garell, JI Choi, Y Chen… - ACS Materials …, 2022 - ACS Publications
Quantifying water and salt transport properties in polyamide is of growing importance as the
use of reverse osmosis membranes grows in many industries. Here, using solid-state …

Two-dimensional NMR spectroscopy reveals cation-triggered backbone degradation in polysulfone-based anion exchange membranes

CG Arges, V Ramani - … of the National Academy of Sciences, 2013 - National Acad Sciences
Anion exchange membranes (AEMs) find widespread applications as an electrolyte and/or
electrode binder in fuel cells, electrodialysis stacks, flow and metal-air batteries, and …

Magnetic resonance microscopy of heterogeneity in polymer electrolyte membranes

SL Codd, DT Howe, JD Seymour, EH Werre… - Applied Magnetic …, 2007 - Springer
Magnetic resonance microscopy of Nafion 117 is used to measure the spatial variation of
solvent dynamics in protonated (acid form) membranes immersed in solvent. Spatial …

Probing Water and Ion Diffusion in Functional Hydrogel Membranes by PFG-NMR

O Nordness, JD Moon, N Marioni, ES Zofchak… - …, 2023 - ACS Publications
The effects of ligand basicity on water and ion transport within hydrogel membranes are
investigated using a library of functionalizable poly (ethylene glycol) diacrylate (PEGDA) …

Transport mechanism of water molecules passing through polyamide/COF mixed matrix membranes

Y Song, M Wei, F Xu, Y Wang - Physical Chemistry Chemical Physics, 2019 - pubs.rsc.org
Mixed matrix membranes (MMMs) have gained significant attention due to their high water
permeability without the cost of salt rejection. However, the mechanism of water transport …