Identification of multiple diffusion rates in mixed solvent anion exchange membranes using high resolution MAS NMR
JE Jenkins, MR Hibbs, TM Alam - Acs Macro Letters, 2012 - ACS Publications
High resolution magic angle spinning (HRMAS) 1H NMR in combination with 2D exchange
NOESY and pulsed field gradient (PFG) NMR diffusion experiments have been used to …
NOESY and pulsed field gradient (PFG) NMR diffusion experiments have been used to …
Characterization of heterogeneous solvent diffusion environments in anion exchange membranes
TM Alam, MR Hibbs - Macromolecules, 2014 - ACS Publications
1H high resolution magic angle spinning (HRMAS) NMR spectroscopy was used to
characterize the solvent environments in a series of poly (phenylene)-and poly (phenylene …
characterize the solvent environments in a series of poly (phenylene)-and poly (phenylene …
Quantitative 1H NMR Analysis of Chemical Stabilities in Anion-Exchange Membranes
SA Nuñez, MA Hickner - Acs Macro Letters, 2013 - ACS Publications
We compared the alkaline stability of three classes of anion exchange membranes that are
leading candidates for applications in platinum-free fuel cells. A methodology is presented …
leading candidates for applications in platinum-free fuel cells. A methodology is presented …
Multiscale tortuous diffusion in anion and cation exchange membranes
LM Thieu, L Zhu, AG Korovich, MA Hickner… - …, 2018 - ACS Publications
A fundamental understanding of water transport and morphology is critical for improving
ionic conductivity in polymer membranes. In a series of random copolymer anion exchange …
ionic conductivity in polymer membranes. In a series of random copolymer anion exchange …
Tracer-Desorption 1H NMR Measurement of Diffusion Coefficients in Polyphosphazene Ion-Exchange Membranes
R Carter, RF Evilia, PN Pintauro - The Journal of Physical …, 2001 - ACS Publications
The growth of an NMR signal due to diffusion of solute out of a thin membrane has been
investigated for the measurement of diffusion rates under conditions that are not suitable for …
investigated for the measurement of diffusion rates under conditions that are not suitable for …
Unraveling water and salt transport in polyamide with nuclear magnetic resonance spectroscopy
M Abbaszadeh, M Garell, JI Choi, Y Chen… - ACS Materials …, 2022 - ACS Publications
Quantifying water and salt transport properties in polyamide is of growing importance as the
use of reverse osmosis membranes grows in many industries. Here, using solid-state …
use of reverse osmosis membranes grows in many industries. Here, using solid-state …
Two-dimensional NMR spectroscopy reveals cation-triggered backbone degradation in polysulfone-based anion exchange membranes
Anion exchange membranes (AEMs) find widespread applications as an electrolyte and/or
electrode binder in fuel cells, electrodialysis stacks, flow and metal-air batteries, and …
electrode binder in fuel cells, electrodialysis stacks, flow and metal-air batteries, and …
Magnetic resonance microscopy of heterogeneity in polymer electrolyte membranes
SL Codd, DT Howe, JD Seymour, EH Werre… - Applied Magnetic …, 2007 - Springer
Magnetic resonance microscopy of Nafion 117 is used to measure the spatial variation of
solvent dynamics in protonated (acid form) membranes immersed in solvent. Spatial …
solvent dynamics in protonated (acid form) membranes immersed in solvent. Spatial …
Probing Water and Ion Diffusion in Functional Hydrogel Membranes by PFG-NMR
The effects of ligand basicity on water and ion transport within hydrogel membranes are
investigated using a library of functionalizable poly (ethylene glycol) diacrylate (PEGDA) …
investigated using a library of functionalizable poly (ethylene glycol) diacrylate (PEGDA) …
Transport mechanism of water molecules passing through polyamide/COF mixed matrix membranes
Mixed matrix membranes (MMMs) have gained significant attention due to their high water
permeability without the cost of salt rejection. However, the mechanism of water transport …
permeability without the cost of salt rejection. However, the mechanism of water transport …