Calcite shape modulation through the lattice mismatch between the self-assembled monolayer template and the nucleated crystal face

B Pokroy, J Aizenberg - CrystEngComm, 2007 - pubs.rsc.org
The shapes of biologically formed calcite crystals are extremely versatile. Numerous studies
have addressed the possible biological mechanism of crystal shape regulation. Synthetic …

Patterned crystallization of calcite in vivo and in vitro

J Aizenberg - Journal of Crystal Growth, 2000 - Elsevier
Biologically formed calcite crystals have unique, sculptured shapes that are believed to be
regulated locally by specific macromolecules and by directional flux of ions into the …

Shape change of calcite single crystals to accommodate interfacial curvature: Crystallization in presence of Mg2+ ions and agarose gel-networks

T Ye, XY Jin, L Chen, C Hu, J Ren, YJ Liu, G Wu… - Chinese Chemical …, 2017 - Elsevier
Synthetic calcite single crystals, due to their strong crystal habit, tend to grow into
characteristic rhombohedra. In the nature, biogenic calcite crystals form composites together …

Control over the vertical growth of single calcitic crystals in biomineralized structures

S Lee, SG Lee, M Sim, D Kwak, JH Park… - Crystal growth & …, 2011 - ACS Publications
Acidic biomacromolecules frequently incorporate into biomineralized structures to control
the morphology and extent of crystal growth. The study of such processes has been …

Effects of chitosan on the alignment, morphology and shape of calcite crystals nucleating under Langmuir monolayers

K Kim, A Uysal, S Kewalramani, B Stripe, P Dutta - CrystEngComm, 2009 - pubs.rsc.org
The growth of calcium carbonate crystals under Langmuir monolayers was investigated in
the presence of chitosan, a soluble derivative of chitin added to the subphase to better …

Structural adaptability in an organic template for CaCO 3 mineralization

E DiMasi, SY Kwak, BP Pichon, NAJM Sommerdijk - CrystEngComm, 2007 - pubs.rsc.org
Biomimetic strategies to control mineral nucleation include the development of self-
assembled monolayers with appropriate structural properties. We present a bis-urea based …

Nanostructure of biogenic calcite crystals: a view by small-angle X-ray scattering

C Gilow, E Zolotoyabko, O Paris, P Fratzl… - Crystal growth & …, 2011 - ACS Publications
One of the most fascinating topics currently being discussed in the field of biomineralization
is the occlusion of organic macromolecules within mineral crystals. It is already known that …

Template-dependent morphogenesis of oriented calcite crystals in the presence of magnesium ions

YJ Han, LM Wysocki, MS Thanawala… - Angewandte Chemie …, 2005 - dash.harvard.edu
This paper presents a study of the morphogenesis of oriented crystals caused by solution
growth modifiers. Self-assembled monolayers of HS-(CH2) 15-CO2H, HS-(CH2) 10-CO2H …

Crystallization on surfaces of well-defined topography

NBJ Hetherington, AN Kulak, K Sheard, FC Meldrum - Langmuir, 2006 - ACS Publications
Single crystals of calcite with regular patterned surfaces comprising close-packed arrays of
hemispherical cavities or domes were produced by crystallization on colloidal monolayers or …

[HTML][HTML] Oriented crystal growth on organic monolayers

JH Harding, CL Freeman, DM Duffy - CrystEngComm, 2014 - pubs.rsc.org
Ordered organic substrates influence the crystallisation of minerals and different crystal
morphologies and polymorphs can be stabilised by varying the properties of the substrates …