Brown carbon formation from nighttime chemistry of unsaturated heterocyclic volatile organic compounds

H Jiang, AL Frie, A Lavi, JY Chen… - … & Technology Letters, 2019 - ACS Publications
Nighttime atmospheric processing enhances the formation of brown carbon aerosol (BrC) in
biomass burning plumes. Heterocyclic compounds, a group of volatile organic compounds …

Formation of Secondary Brown Carbon in Biomass Burning Aerosol Proxies through NO3 Radical Reactions

C Li, Q He, APS Hettiyadura, U Käfer… - … science & technology, 2019 - ACS Publications
Atmospheric brown carbon (BrC) is an important contributor to the radiative forcing of climate
by organic aerosols. Because of the molecular diversity of BrC compounds and their …

Evolution of the light-absorption properties of combustion brown carbon aerosols following reaction with nitrate radicals

Z Cheng, KM Atwi, Z Yu, A Avery… - Aerosol Science and …, 2020 - Taylor & Francis
Polycyclic aromatic hydrocarbons (PAHs) are important constituents of brown carbon (BrC)
that are subject to atmospheric processing by gas-phase oxidants such as the hydroxyl …

Relationship between oxidation level and optical properties of secondary organic aerosol

AT Lambe, CD Cappa, P Massoli… - … science & technology, 2013 - ACS Publications
Brown carbon (BrC), which may include secondary organic aerosol (SOA), can be a
significant climate-forcing agent via its optical absorption properties. However, the overall …

Molecular chemistry of atmospheric brown carbon inferred from a nationwide biomass burning event

P Lin, N Bluvshtein, Y Rudich… - Environmental …, 2017 - ACS Publications
Lag Ba'Omer, a nationwide bonfire festival in Israel, was chosen as a case study to
investigate the influence of a major biomass burning event on the light absorption properties …

Chemical structure regulates the formation of secondary organic aerosol and brown carbon in nitrate radical oxidation of pyrroles and methylpyrroles

R Mayorga, K Chen, N Raeofy, M Woods… - Environmental …, 2022 - ACS Publications
Nitrogen-containing heterocyclic volatile organic compounds (VOCs) are important
components of wildfire emissions that are readily reactive toward nitrate radicals (NO3) …

Molecular characterization of brown carbon (BrC) chromophores in secondary organic aerosol generated from photo-oxidation of toluene

P Lin, J Liu, JE Shilling, SM Kathmann… - Physical Chemistry …, 2015 - pubs.rsc.org
Atmospheric brown carbon (BrC) is a significant contributor to light absorption and climate
forcing. However, little is known about a fundamental relationship between the chemical …

Contribution of carbonyl chromophores in secondary brown carbon from nighttime oxidation of unsaturated heterocyclic volatile organic compounds

K Chen, R Mayorga, C Hamilton… - Environmental …, 2023 - ACS Publications
The light absorption properties of brown carbon (BrC), which are linked to molecular
chromophores, may play a significant role in the Earth's energy budget. While nitroaromatic …

Formation of secondary organic aerosol from nitrate radical oxidation of phenolic VOCs: Implications for nitration mechanisms and brown carbon formation

RJ Mayorga, Z Zhao, H Zhang - Atmospheric Environment, 2021 - Elsevier
Volatile phenolic derivatives are substantially emitted from biomass burning and produced
from photochemistry of atmospheric aromatic volatile organic compounds (VOCs). Oxidation …

Effect of solar radiation on the optical properties and molecular composition of laboratory proxies of atmospheric brown carbon

HJ Lee, PK Aiona, A Laskin, J Laskin… - … science & technology, 2014 - ACS Publications
Sources, optical properties, and chemical composition of atmospheric brown carbon (BrC)
aerosol are uncertain, making it challenging to estimate its contribution to radiative forcing …