Field-Induced Co(II) Single-Ion Magnets with mer-Directing Ligands but Ambiguous Coordination Geometry
Y Peng, V Mereacre, CE Anson, Y Zhang… - Inorganic …, 2017 - ACS Publications
Three air-stable Co (II) mononuclear complexes with different aromatic substituents have
been prepared and structurally characterized by single-crystal X-ray diffraction. The …
been prepared and structurally characterized by single-crystal X-ray diffraction. The …
Structure, magnetic anisotropy and relaxation behavior of seven-coordinate Co (ii) single-ion magnets perturbed by counter-anions
G Yi, C Zhang, W Zhao, H Cui, L Chen, Z Wang… - Dalton …, 2020 - pubs.rsc.org
A series of mononuclear seven-coordinate Co (II) complexes [CoII (BPA-TPA)](ClO4) 2· H2O
(2-ClO4),[CoII (BPA-TPA)](PF6) 2 (3-PF6) and [CoII (BPA-TPA)](BPh4) 2 (4-BPh4) have …
(2-ClO4),[CoII (BPA-TPA)](PF6) 2 (3-PF6) and [CoII (BPA-TPA)](BPh4) 2 (4-BPh4) have …
Single‐Ion Magnetic Behavior in CoII–CoIII Mixed‐Valence Dinuclear and Pseudodinuclear Complexes
Two CoII–CoIII mixed‐valance complexes of molecular formulas [Co2 (H2L) 2 (H2O) 2][Co2
(H2L) 2 (H2O)(m‐phth)]· 8 (H2O){1; H2L2–= 2‐[(2‐hydroxy‐3‐methoxybenzylidene) amino] …
(H2L) 2 (H2O)(m‐phth)]· 8 (H2O){1; H2L2–= 2‐[(2‐hydroxy‐3‐methoxybenzylidene) amino] …
Tuning the coordination geometry and magnetic relaxation of Co (II) single-ion magnets by varying the ligand substitutions
G Peng, YF Qian, ZW Wang, Y Chen… - Crystal Growth & …, 2021 - ACS Publications
Three mononuclear Co (II) complexes with the formulas of [Co (L1) 2](1),[Co (L2) 2 (CH3OH)
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …
Field-induced single-ion magnet behaviour of a hexacoordinated Co (II) complex with easy-axis-type magnetic anisotropy
YP Tupolova, IN Shcherbakov, LD Popov… - Dalton …, 2019 - pubs.rsc.org
A coordination compound with the composition [CoLCl2]· H2O (L= bis-condensation product
of diacetyl and 2-hydrazinyl-4, 6-dimethylpyrimidine) was synthesized, in which the Co (II) …
of diacetyl and 2-hydrazinyl-4, 6-dimethylpyrimidine) was synthesized, in which the Co (II) …
Probing the effect of axial ligands on easy-plane anisotropy of pentagonal-bipyramidal cobalt (II) single-ion magnets
We herein reported the synthetic, structural, computational, and magnetic studies of four air-
stable heptacoordinated mononuclear cobalt (II) complexes, namely,[CoII (tdmmb)(H2O) …
stable heptacoordinated mononuclear cobalt (II) complexes, namely,[CoII (tdmmb)(H2O) …
Magnetic properties of two coordination isomeric cobalt (II) single-ion magnets
HH Cui, HJ Xu, T Zhang, S Luo, W Tong, M Wang… - Dalton …, 2023 - pubs.rsc.org
Two isomeric Co (II) complexes with the same general molecular formula of [Co (napy) 2
(NO3) 2](napy= 1, 8-naphthyridine) have been synthesized. X-ray single crystal structural …
(NO3) 2](napy= 1, 8-naphthyridine) have been synthesized. X-ray single crystal structural …
Magnetic Anisotropy and Relaxation in Four-Coordinate Cobalt(II) Single-Ion Magnets with a [CoIIO4] Core
HH Cui, H Xu, T Zhang, Q Chen, S Luo… - Inorganic …, 2024 - ACS Publications
A mononuclear four-coordinate Co (II) complex with a [CoIIO4] core, namely, PPN [Li
(MeOH) 4][Co (L) 2](1)(PPN= bis (phosphoranediyl) iminium; H2L= perfluoropinacol), has …
(MeOH) 4][Co (L) 2](1)(PPN= bis (phosphoranediyl) iminium; H2L= perfluoropinacol), has …
Probing the effects of ligand field and coordination geometry on magnetic anisotropy of pentacoordinate Cobalt (II) single-ion magnets
In this work, the effects of ligand field strength as well as the metal coordination geometry on
magnetic anisotropy of pentacoordinated CoII complexes have been investigated using a …
magnetic anisotropy of pentacoordinated CoII complexes have been investigated using a …
Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co (ii) single-ion magnets
B Zhang, Y Zhou, HY Huang, XL Zhang… - Inorganic Chemistry …, 2024 - pubs.rsc.org
The mononuclear cobalt (II) complexes [Co (LN8)](BPh4) 2· C4H10O (1-BPh4) and [Co
(LN8)](NO3) 2· CH3CN (2-NO3)(LN8= 1, 4, 7, 10-tetrakis (2-pyridinemethyl)-1, 4, 7, 10 …
(LN8)](NO3) 2· CH3CN (2-NO3)(LN8= 1, 4, 7, 10-tetrakis (2-pyridinemethyl)-1, 4, 7, 10 …
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- ligand field coordination geometry
- magnetic relaxation coordination geometry
- magnetic anisotropy ion magnet
- magnetic anisotropy ligand field
- theory and experiment ion magnet
- pentacoordinate cobalt coordination geometry
- pentacoordinate cobalt ligand field
- ligand substitutions coordination geometry
- magnetic anisotropy coordination geometry