Pulsed field gradient NMR diffusion measurement in nanoporous materials

J Kärger, M Avramovska, D Freude, J Haase, S Hwang… - Adsorption, 2021 - Springer
Labeling in diffusion measurements by pulsed field gradient (PFG) NMR is based on the
observation of the phase of nuclear spins acquired in a constant magnetic field with …

Diffusion in nanoporous materials: novel insights by combining MAS and PFG NMR

J Kärger, D Freude, J Haase - Processes, 2018 - mdpi.com
Pulsed field gradient (PFG) nuclear magnetic resonance (NMR) allows recording of
molecular diffusion paths (notably, the probability distribution of molecular displacements …

New options for measuring molecular diffusion in zeolites by MAS PFG NMR

A Pampel, M Fernandez, D Freude, J Kärger - Chemical physics letters, 2005 - Elsevier
Combination of pulsed field gradient (PFG) NMR with magic-angle spinning (MAS) NMR is
demonstrated to have remarkable advantages in comparison with conventional PFG NMR, if …

Boundary effects of molecular diffusion in nanoporous materials: a pulsed field gradient nuclear magnetic resonance study

O Geier, RQ Snurr, F Stallmach, J Kärger - The Journal of chemical …, 2004 - pubs.aip.org
The boundary conditions of intraparticle diffusion in nanoporous materials may be chosen to
approach the limiting cases of either absorbing or reflecting boundaries, depending on the …

The impact of mesopores on mass transfer in nanoporous materials: evidence of diffusion measurement by NMR

R Valiullin, J Kärger - Chemie Ingenieur Technik, 2011 - Wiley Online Library
The purposeful incorporation of mesopores has become an important issue of the synthesis
and post‐synthesis modification of nanoporous solids for generating transport‐optimized …

The potentials of pulsed field gradient NMR for investigation of porous media

F Stallmach, J Kärger - Adsorption, 1999 - Springer
PFG NMR self-diffusion studies provide information on the translational mobility of fluid
molecules. Since in porous media the diffusion path of fluid molecules in the pore space is …

Spin echo NMR diffusion studies

F Stallmach, P Galvosas - Annual reports on NMR spectroscopy, 2007 - Elsevier
The basic principles of NMR diffusion studies and a generalized approach to calculate NMR
spin echo attenuation due to diffusion in the presence of gradients of the polarizing magnetic …

Microscopic anisotropy revealed by NMR double pulsed field gradient experiments with arbitrary timing parameters

E Özarslan, PJ Basser - The Journal of chemical physics, 2008 - pubs.aip.org
We consider a general double pulsed field gradient experiment with arbitrary experimental
parameters and calculate an exact expression for the NMR signal attenuation from restricted …

In situ study on molecular diffusion phenomena in nanoporous catalytic solids

C Chmelik, J Kärger - Chemical Society Reviews, 2010 - pubs.rsc.org
As an omnipresent phenomenon in nature, diffusion is among the rate-determining
processes in many technological processes. This is in particular true for catalytic conversion …

Exploring the hierarchy of transport phenomena in hierarchical pore systems by NMR diffusion measurement

D Mehlhorn, R Valiullin, J Kärger, K Cho… - … and mesoporous materials, 2012 - Elsevier
The pulsed field gradient technique of NMR (PFG NMR) is applied for exploring molecular
diffusion in different specimens of zeolite NaCaA, notably in samples containing …