Transition metal-catalyzed C–H amination at positions adjacent to double bonds and
carbonyl groups is discussed in this critical review. While the focus will center on the recent …

Conspectus The catalytic activation and functionalization of unactivated C (sp3)–H bonds of
alkyl groups has undergone intense development in recent years. In particular, a variety of …

Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

The development of a ligand-assisted Pd-catalyzed C–H alkenylation of aliphatic amines is
reported. Our studies indicated that an amino-acid-derived ligand renders the C–H bond …

Abstract 2, 4, 6‐Trimethoxypyridine is identified as an efficient ligand for promoting a Pd‐
catalyzed ortho‐C H amination of both benzamides and triflyl‐protected benzylamines …

Palladium-catalysis has been broadly applied to sp2 C–H activation. Recently, palladium-
catalyzed sp3 C–H activation has also been considered as an important strategy to construct …

Abstract Palladium-catalysed C (sp 2)–N cross-coupling (that is, Buchwald–Hartwig
amination) is employed widely in synthetic chemistry, including in the pharmaceutical …

C–H amination of N-aryl benzamides with O-benzoyl hydroxylamines has been achieved
with either Pd (II) or Pd (0) catalysts. Furthermore, we demonstrate that secondary amines …

Nitrogen‐containing organic compounds are valuable in many fields of science and
industry. The most reliable method for the construction of C (sp2)–N bonds is undoubtedly …

The development of methods for the direct conversion of carbonshydrogen bonds into
carbon-oxygen, carbon-halogen, carbon-nitrogen, carbon-sulfur, and carbon-carbon bonds …