Highly Efficient Syntheses of Azetidines, Pyrrolidines, and Indolines via Palladium Catalyzed Intramolecular Amination of C(sp3)–H and C(sp2)–H Bonds at γ and δ …
G He, Y Zhao, S Zhang, C Lu… - Journal of the American …, 2012 - ACS Publications
Efficient methods have been developed to synthesize azetidine, pyrrolidine, and indoline
compounds via palladium-catalyzed intramolecular amination of C–H bonds at the γ and δ …
compounds via palladium-catalyzed intramolecular amination of C–H bonds at the γ and δ …
Recent advances in palladium-catalyzed C (sp3)–H activation for the formation of carbon–carbon and carbon–heteroatom bonds
N Dastbaravardeh, M Christakakou, M Haider… - …, 2014 - thieme-connect.com
Within this review, recent developments in the field of C (sp 3)–H activation catalyzed by
palladium are discussed. Both intra-and intermolecular reactions towards carbon–carbon …
palladium are discussed. Both intra-and intermolecular reactions towards carbon–carbon …
Cross‐Coupling of C(sp3)–H Bonds with Organometallic Reagents via Pd(II)/Pd(0) Catalysis
Palladium‐catalyzed C–H activation/C–C bond‐forming reactions have emerged as a
promising class of synthetic tools in organic chemistry. Among the many different means of …
promising class of synthetic tools in organic chemistry. Among the many different means of …
Palladium-Catalyzed Picolinamide-Directed Alkylation of Unactivated C(sp3)–H Bonds with Alkyl Iodides
SY Zhang, G He, WA Nack, Y Zhao, Q Li… - Journal of the American …, 2013 - ACS Publications
We report an efficient method for the alkylation of γ-C (sp3)–H bonds of picolinamide-
protected aliphatic amine substrates with primary alkyl iodides via palladium catalysis …
protected aliphatic amine substrates with primary alkyl iodides via palladium catalysis …
Utilizing Carbonyl Coordination of Native Amides for Palladium‐Catalyzed C(sp3)−H Olefination
Abstract PdII‐catalyzed C (sp3)− H olefination of weakly coordinating native amides is
reported. Three major drawbacks of previous C (sp3)− H olefination protocols, 1) in situ …
reported. Three major drawbacks of previous C (sp3)− H olefination protocols, 1) in situ …
Controlling Reactivity and Selectivity in the Nondirected C–H Activation of Arenes with Palladium
S Kaltenberger, M van Gemmeren - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Aromatic structures are widespread motifs throughout organic chemistry, and C–
H activation has been recognized as a major tool for enabling their sustainable and efficient …
H activation has been recognized as a major tool for enabling their sustainable and efficient …
Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation
CL Sun, BJ Li, ZJ Shi - Chemical communications, 2010 - pubs.rsc.org
Direct selective palladium catalyzed C–H functionalization has become a highly attractive
strategy in organic synthesis and represents a highly desirable goal. Compared with cross …
strategy in organic synthesis and represents a highly desirable goal. Compared with cross …
Ligand-controlled, tunable silver-catalyzed C–H amination
JM Alderson, AM Phelps, RJ Scamp… - Journal of the …, 2014 - ACS Publications
The development of readily tunable and regioselective C–H functionalization reactions that
operate solely through catalyst control remains a challenge in modern organic synthesis …
operate solely through catalyst control remains a challenge in modern organic synthesis …
Synthesis of Indolines by Palladium-Catalyzed Intermolecular Amination of Unactivated C(sp3)–H Bonds
X Sun, Z Wu, W Qi, X Ji, C Cheng, Y Zhang - Organic letters, 2019 - ACS Publications
A new palladium-catalyzed C (sp3)–H amination reaction has been developed. 1-(tert-Butyl)-
2-iodobenzene and its derivatives undergo palladium-catalyzed C–H activation to form …
2-iodobenzene and its derivatives undergo palladium-catalyzed C–H activation to form …
Carboxylate Ligand-Exchanged Amination/C(sp3)–H Arylation Reaction via Pd/Norbornene Cooperative Catalysis
This report describes a carboxylate ligand exchange strategy that was used to achieve a
Catellani reaction consisting of amination/unactivated aliphatic C–H arylation. Pivalic acid …
Catellani reaction consisting of amination/unactivated aliphatic C–H arylation. Pivalic acid …