Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co (ii) single-ion magnets
B Zhang, Y Zhou, HY Huang, XL Zhang… - Inorganic Chemistry …, 2024 - pubs.rsc.org
The mononuclear cobalt (II) complexes [Co (LN8)](BPh4) 2· C4H10O (1-BPh4) and [Co
(LN8)](NO3) 2· CH3CN (2-NO3)(LN8= 1, 4, 7, 10-tetrakis (2-pyridinemethyl)-1, 4, 7, 10 …
(LN8)](NO3) 2· CH3CN (2-NO3)(LN8= 1, 4, 7, 10-tetrakis (2-pyridinemethyl)-1, 4, 7, 10 …
Optimal N–Co–N bite angle for enhancing the magnetic anisotropy of zero-field Co (II) single-ion magnets in tetrahedral [N4] coordination environment
M Wang, YQ Zhang, L Chen - Journal of Solid State Chemistry, 2021 - Elsevier
By modulating the substitution on the oxamide ligand, a mononuclear tetrahedral Co (II)
complex (HNEt 3) 2 [CoL 2](1)(H 2 L= N, N′-bis (methanesulfonyl) oxamide) with subtle …
complex (HNEt 3) 2 [CoL 2](1)(H 2 L= N, N′-bis (methanesulfonyl) oxamide) with subtle …
Modulation of the magnetic anisotropy of octahedral cobalt (II) single-ion magnets by fine-tuning the axial coordination microenvironment
Y Wu, D Tian, J Ferrando-Soria, J Cano, L Yin… - Inorganic Chemistry …, 2019 - pubs.rsc.org
Two mononuclear cobalt (II) complexes, with the formulas [Co (2, 6-dfba) 2 (bpp) 2 (H2O) 2]
n (1) and [Co (2, 6-dfba) 2 (bpe) 2 (H2O) 2] n (2)(2, 6-Hdfba= 2, 6-difluorobenzoic acid, bpp …
n (1) and [Co (2, 6-dfba) 2 (bpe) 2 (H2O) 2] n (2)(2, 6-Hdfba= 2, 6-difluorobenzoic acid, bpp …
Tuning the coordination geometry and magnetic relaxation of Co (II) single-ion magnets by varying the ligand substitutions
G Peng, YF Qian, ZW Wang, Y Chen… - Crystal Growth & …, 2021 - ACS Publications
Three mononuclear Co (II) complexes with the formulas of [Co (L1) 2](1),[Co (L2) 2 (CH3OH)
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …
Magnetic Anisotropy and Relaxation in Four-Coordinate Cobalt(II) Single-Ion Magnets with a [CoIIO4] Core
HH Cui, H Xu, T Zhang, Q Chen, S Luo… - Inorganic …, 2024 - ACS Publications
A mononuclear four-coordinate Co (II) complex with a [CoIIO4] core, namely, PPN [Li
(MeOH) 4][Co (L) 2](1)(PPN= bis (phosphoranediyl) iminium; H2L= perfluoropinacol), has …
(MeOH) 4][Co (L) 2](1)(PPN= bis (phosphoranediyl) iminium; H2L= perfluoropinacol), has …
On balancing the QTM and the direct relaxation processes in single-ion magnets–the importance of symmetry control
YF Deng, T Han, B Yin, YZ Zheng - Inorganic Chemistry Frontiers, 2017 - pubs.rsc.org
Two mononuclear trigonal-planar Co (II) complexes [Na (THF) 6][Co (OAr) 3] 1 and [(THF)
3NaCo (OAr) 3] 2 (OAr−= 2, 6-di-tert-butylphenoxo, THF= tetrahydrofuran) with the same …
3NaCo (OAr) 3] 2 (OAr−= 2, 6-di-tert-butylphenoxo, THF= tetrahydrofuran) with the same …
Probing the effect of axial ligands on easy-plane anisotropy of pentagonal-bipyramidal cobalt (II) single-ion magnets
We herein reported the synthetic, structural, computational, and magnetic studies of four air-
stable heptacoordinated mononuclear cobalt (II) complexes, namely,[CoII (tdmmb)(H2O) …
stable heptacoordinated mononuclear cobalt (II) complexes, namely,[CoII (tdmmb)(H2O) …
Tuning of Dimensionality and Nuclearity as a Function of Ligand Field Modulation Resulting in Field-Induced Cobalt (II) Single-Ion Magnet
SM Hossain, S Kamilya, S Ghosh… - Crystal Growth & …, 2023 - ACS Publications
The present study reveals that predetermined diverse topology and desired properties can
be achieved by strategically designing the ligand and it confirms that the structural and …
be achieved by strategically designing the ligand and it confirms that the structural and …
Fine‐Tuning of Structural Distortion and Magnetic Anisotropy by Organosulfonates in Octahedral Cobalt (II) Complexes
D Shao, FX Xu, L Yin, HQ Li, YC Sun… - Chinese Journal of …, 2022 - Wiley Online Library
Comprehensive Summary Precise modulation of the magnetic anisotropy of metal ions
remains highly important for the development of high–performance single‐molecule …
remains highly important for the development of high–performance single‐molecule …
Cobalt(II)-Based Single-Ion Magnets with Distorted Pseudotetrahedral [N2O2] Coordination: Experimental and Theoretical Investigations
S Ziegenbalg, D Hornig, H Görls, W Plass - Inorganic Chemistry, 2016 - ACS Publications
The synthesis and magnetic properties of cobalt (II) complexes with sterically demanding
Schiff-base ligands are reported. The compounds [Co (LBr) 2](1) and [Co (LPh) 2]· CH2Cl2 …
Schiff-base ligands are reported. The compounds [Co (LBr) 2](1) and [Co (LPh) 2]· CH2Cl2 …