Magnetic Anisotropy and Relaxation in Four-Coordinate Cobalt(II) Single-Ion Magnets with a [CoIIO4] Core
HH Cui, H Xu, T Zhang, Q Chen, S Luo… - Inorganic …, 2024 - ACS Publications
A mononuclear four-coordinate Co (II) complex with a [CoIIO4] core, namely, PPN [Li
(MeOH) 4][Co (L) 2](1)(PPN= bis (phosphoranediyl) iminium; H2L= perfluoropinacol), has …
(MeOH) 4][Co (L) 2](1)(PPN= bis (phosphoranediyl) iminium; H2L= perfluoropinacol), has …
Influence of F-position and solvent on coordination geometry and single ion magnet behavior of Co (ii) complexes
Y Chen, Q Yang, G Peng, YQ Zhang, XM Ren - Dalton Transactions, 2021 - pubs.rsc.org
Three mononuclear Co (II) complexes with the compositions of [Co (L1) 2](1),[Co (L2) 2
(CH3CN)](2) and [Co (L3) 2](3)(HL1= 2-((E)-(2-fluorobenzylimino) methyl)-4, 6 …
(CH3CN)](2) and [Co (L3) 2](3)(HL1= 2-((E)-(2-fluorobenzylimino) methyl)-4, 6 …
Structure, magnetic anisotropy and relaxation behavior of seven-coordinate Co (ii) single-ion magnets perturbed by counter-anions
G Yi, C Zhang, W Zhao, H Cui, L Chen, Z Wang… - Dalton …, 2020 - pubs.rsc.org
A series of mononuclear seven-coordinate Co (II) complexes [CoII (BPA-TPA)](ClO4) 2· H2O
(2-ClO4),[CoII (BPA-TPA)](PF6) 2 (3-PF6) and [CoII (BPA-TPA)](BPh4) 2 (4-BPh4) have …
(2-ClO4),[CoII (BPA-TPA)](PF6) 2 (3-PF6) and [CoII (BPA-TPA)](BPh4) 2 (4-BPh4) have …
On balancing the QTM and the direct relaxation processes in single-ion magnets–the importance of symmetry control
YF Deng, T Han, B Yin, YZ Zheng - Inorganic Chemistry Frontiers, 2017 - pubs.rsc.org
Two mononuclear trigonal-planar Co (II) complexes [Na (THF) 6][Co (OAr) 3] 1 and [(THF)
3NaCo (OAr) 3] 2 (OAr−= 2, 6-di-tert-butylphenoxo, THF= tetrahydrofuran) with the same …
3NaCo (OAr) 3] 2 (OAr−= 2, 6-di-tert-butylphenoxo, THF= tetrahydrofuran) with the same …
Investigation of easy-plane magnetic anisotropy in P-ligand square-pyramidal Co II single ion magnets
In this work we report two pentacoordinated CoII–P4X1 Single Ion Magnets (SIMs) based on
P-donor ligands. The tetradentate ligand tris [2-(diphenylphosphino) ethyl] phosphine allows …
P-donor ligands. The tetradentate ligand tris [2-(diphenylphosphino) ethyl] phosphine allows …
Probing the Magnetic Anisotropy of Co (II) Complexes Featuring Redox-Active Ligands
P Kumar, DJ SantaLucia… - Inorganic …, 2020 - ACS Publications
Coordination complexes that possess large magnetic anisotropy (otherwise known as zero-
field splitting, ZFS) have possible applications in the field of magnetic materials, including …
field splitting, ZFS) have possible applications in the field of magnetic materials, including …
2-Formylphenoxyacetic acid Schiff bases: a promising ligand scaffold for readily available trigonal prismatic Co (ii) single-ion magnets
K Kotrle, I Nemec, P Antal, K Petrželová… - Inorganic Chemistry …, 2023 - pubs.rsc.org
This article presents a series of six mononuclear Co (II) complexes 1–6 featuring ligands
derived from a hexadentate Schiff base family, originating from the condensation of (2 …
derived from a hexadentate Schiff base family, originating from the condensation of (2 …
Zero-Field SMM Behavior Triggered by Magnetic Exchange Interactions and a Collinear Arrangement of Local Anisotropy Axes in a Linear Co3II Complex
A Zabala-Lekuona, A Landart-Gereka… - Inorganic …, 2023 - ACS Publications
A new linear trinuclear Co (II) 3 complex with a formula of [{Co (μ-L)} 2Co] has been
prepared by self-assembly of Co (II) ions and the N3O3-tripodal Schiff base ligand H3L …
prepared by self-assembly of Co (II) ions and the N3O3-tripodal Schiff base ligand H3L …
Magnetic anisotropy of a Co II single ion magnet with distorted trigonal prismatic coordination: theory and experiment
The single ion magnetic properties of Co (II) are affected by the details of the coordination
geometry of the ion. Here we show that a geometry close to trigonal prismatic which arises …
geometry of the ion. Here we show that a geometry close to trigonal prismatic which arises …
Fine‐Tuning of Structural Distortion and Magnetic Anisotropy by Organosulfonates in Octahedral Cobalt (II) Complexes
D Shao, FX Xu, L Yin, HQ Li, YC Sun… - Chinese Journal of …, 2022 - Wiley Online Library
Comprehensive Summary Precise modulation of the magnetic anisotropy of metal ions
remains highly important for the development of high–performance single‐molecule …
remains highly important for the development of high–performance single‐molecule …