Tuning the coordination geometry and magnetic relaxation of Co (II) single-ion magnets by varying the ligand substitutions
G Peng, YF Qian, ZW Wang, Y Chen… - Crystal Growth & …, 2021 - ACS Publications
Three mononuclear Co (II) complexes with the formulas of [Co (L1) 2](1),[Co (L2) 2 (CH3OH)
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …
Switching of easy-axis to easy-plane anisotropy in cobalt (II) complexes
Y Wu, J Xi, T Xiao, J Ferrando-Soria… - Inorganic Chemistry …, 2021 - pubs.rsc.org
A tetranuclear cubane-type complex [Co4 (ntfa) 4 (CH3O) 4 (CH3OH) 4](1) with a {Co4O4}
core, and a mononuclear complex [Co (ntfa) 2 (CH3OH) 2](2) have been rationally obtained …
core, and a mononuclear complex [Co (ntfa) 2 (CH3OH) 2](2) have been rationally obtained …
Magneto-Structural Correlations in a Series of Pseudotetrahedral [CoII(XR)4]2– Single Molecule Magnets: An ab Initio Ligand Field Study
EA Suturina, D Maganas, E Bill, M Atanasov… - Inorganic …, 2015 - ACS Publications
Over the past several decades, tremendous efforts have been invested in finding molecules
that display slow relaxation of magnetization and hence act as single-molecule magnets …
that display slow relaxation of magnetization and hence act as single-molecule magnets …
Slow magnetic relaxation in penta-coordinate cobalt (II) field-induced single-ion magnets (SIMs) with easy-axis magnetic anisotropy
SS Massoud, ZE Perez, JR Courson, RC Fischer… - Dalton …, 2020 - pubs.rsc.org
Two penta-coordinate complexes of the general formula [Co (Ln)(NCS)] ClO4, where
L1={bis [(3, 5-dimethyl-1H-pyrazol-1-yl) ethyl]-[(3, 4-dimethoxypyridin-2-yl) methyl]} amine …
L1={bis [(3, 5-dimethyl-1H-pyrazol-1-yl) ethyl]-[(3, 4-dimethoxypyridin-2-yl) methyl]} amine …
What controls the sign and magnitude of magnetic anisotropy in tetrahedral cobalt (II) single-ion magnets?
A family of mononuclear tetrahedral cobalt (II) thiourea complexes,[Co (L1) 4](NO3) 2 (1)
and [Co (L x) 4](ClO4) 2 where x= 2 (2), 3 (3), 4 (4)(where L1= thiourea, L2= 1, 3 …
and [Co (L x) 4](ClO4) 2 where x= 2 (2), 3 (3), 4 (4)(where L1= thiourea, L2= 1, 3 …
Two polymorphic Co (II) field-induced single-ion magnets with enormous angular distortion from the ideal octahedron
A mononuclear complex [Co (neo)(PhCOO) 2,], neo= neocuproine, PhCOO−= the benzoate
anion, was prepared in two polymorph forms crystallizing in the C2/c,(1) and P21/c,(2) space …
anion, was prepared in two polymorph forms crystallizing in the C2/c,(1) and P21/c,(2) space …
Tuning of Dimensionality and Nuclearity as a Function of Ligand Field Modulation Resulting in Field-Induced Cobalt (II) Single-Ion Magnet
SM Hossain, S Kamilya, S Ghosh… - Crystal Growth & …, 2023 - ACS Publications
The present study reveals that predetermined diverse topology and desired properties can
be achieved by strategically designing the ligand and it confirms that the structural and …
be achieved by strategically designing the ligand and it confirms that the structural and …
Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
Single‐Ion Magnetic Behavior in CoII–CoIII Mixed‐Valence Dinuclear and Pseudodinuclear Complexes
Two CoII–CoIII mixed‐valance complexes of molecular formulas [Co2 (H2L) 2 (H2O) 2][Co2
(H2L) 2 (H2O)(m‐phth)]· 8 (H2O){1; H2L2–= 2‐[(2‐hydroxy‐3‐methoxybenzylidene) amino] …
(H2L) 2 (H2O)(m‐phth)]· 8 (H2O){1; H2L2–= 2‐[(2‐hydroxy‐3‐methoxybenzylidene) amino] …
Pentacoordinate cobalt (II) complexes with neutral tripodal N-donor ligands: Zero-field splitting for a distorted trigonal bipyramidal geometry
SS Massoud, RC Fischer, FA Mautner, MM Parfait… - Inorganica Chimica …, 2018 - Elsevier
A series of pentacoordinate Co (II) complexes of the composition [Co (bpdmpz) Cl] ClO 4
(1),[Co (bpdmpz) Cl] PF 6 (2),[Co (bdmpzp) Cl] ClO 4· H 2 O (3),[Co (bdmpzp) Cl] PF 6 …
(1),[Co (bpdmpz) Cl] PF 6 (2),[Co (bdmpzp) Cl] ClO 4· H 2 O (3),[Co (bdmpzp) Cl] PF 6 …