To gain a better insight into the factors affecting the enhancement of the energy barrier in
single molecule (single ion) magnets, three hexacoordinate cobalt (II) complexes based on …

Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …

A series of pentacoordinate Co (II) complexes of the composition [Co (bpdmpz) Cl] ClO 4
(1),[Co (bpdmpz) Cl] PF 6 (2),[Co (bdmpzp) Cl] ClO 4· H 2 O (3),[Co (bdmpzp) Cl] PF 6 …

The preparation, X-ray crystal structure, spectroscopic and variable-temperature dc and ac
magnetic properties of two six-coordinate cobalt (II) complexes of formula [Co (bim) 4 (tcm) …

By elaborately employing a rigid tetrazo macrocyclic ligand, both the designed Co (II)
complexes [Co (12-TMC) Py](BF4) 2 (1) and [Co (12-TMC) DMF](BF4) Cl (2)(12-TMC= 1, 4 …

The synthesis and magnetic properties of cobalt (II) complexes with sterically demanding
Schiff-base ligands are reported. The compounds [Co (LBr) 2](1) and [Co (LPh) 2]· CH2Cl2 …

High-coordinate 3d single-ion magnets (SIMs) especially with pentagonal bipyramidal
geometry as an emerging class of representative molecular magnets have received …

In this study, we report the syntheses and structures of two new mononuclear coordination
complexes ([Co (H2pimdc) 2 (phen)] n (1) and [Fe (H2pimdc) 2 (phen)] n (2), H2pimdc= 2 …

Herein a 1D Co (II) coordination polymer of formula [Co (η1-L1)(η2-L1)(py) 2 (H2O)] n
(CoCP) has been synthesised using the rigid H2L1 proligand, containing a long spacer …

Three pentacoordinate complexes of the type [Co (pypz) X2], where pypz is a tridentate
ligand 2, 6-bis (pyrazol-1-yl) pyridine and X= Cl–(1), NCS–(2), and NCO–(3), have been …