[PDF][PDF] Catalysis of electrochemical reactions at redox polymer electrodes: effect of the film thickness

CP Andrieux, JM Dumas-Bouchiat… - … Chemistry and Interfacial …, 1980 - academia.edu
Catalysis of electrochemical reactions at redox polymer electrodes [1--4] has been and is
still one of the major motivations for their synthesis and the investigation of their electriCal …

Catalysis of electrochemical reactions at redox polymer electrodes: Kinetic model for stationary voltammetric techniques

CP Andrieux, JM Dumas-Bouchiat… - Journal of Electroanalytical …, 1982 - Elsevier
A kinetic model describing the catalytic activity of redox polymer film electrodes is presented
and discussed for reaction schemes in which the primary reaction between the active form of …

[引用][C] Heterogeneous (chemically modified electrodes, polymer electrodes) vs. homogeneous catalysis of electrochemical reactions

CP Andrieux, JM Saveant - Journal of Electroanalytical Chemistry and …, 1978 - Elsevier
Homogeneous catalysis of electrochemical reductions (or oxidations) involves essentially
two types of processes [1]. In chemical catalysis the key step is the formation of an adduct …

Electrodeposition of redox polymers and co‐electrodeposition of enzymes by coordinative crosslinking

Z Gao, G Binyamin, HH Kim, SC Barton… - Angewandte …, 2002 - Wiley Online Library
The electrodeposition of metals and electron-or holeconducting polymers proceeds through
forming metallic or covalent bonds, respectively. We show here that films of hydrated redox …

Oligo (ethylene glycol)-Spacered Siloxane Redox Polymers: Highly Diffusive Media for Electrochemical Redox Catalysis

A Merz, H Bachmann - Journal of the American Chemical Society, 1995 - ACS Publications
Redox-modified oligosiloxanes were prepared from an Si6o oligo (hydrogen siloxane) and
allyl-terminated oligo (ethyleneglycol)(OEG) esters of 3-carboxy-2, 2, 5, 5-tetramethyl-A3 …

Electrocatalysis at redox polymer electrodes with separation of the catalytic and charge propagation roles. Reduction of dioxygen to hydrogen peroxide as catalyzed …

FC Anson, CL Ni, JM Saveant - Journal of the American Chemical …, 1985 - ACS Publications
The kinetics of the reduction of 02 by Ru (NH3) 62+ as catalyzed by cobalt (II) tefakis (4-A'-
methylpyridyl) porphyrin are described both in homogeneous solution and when the …

[引用][C] Catalysis at redox polymer coated electrodes

CP Andrieux, JM Saveant - Molecular …, 1992 - John Wiley & Sons: New York, NY

Stabilizing redox polymer films by electrochemically induced crosslinking

S Pöller, D Koster, W Schuhmann - Electrochemistry communications, 2013 - Elsevier
Electrochemically induced crosslinking is suggested to stabilize electrodeposition
polymer/enzyme films selectively on an electrode surface. 4 different protected diamine or …

Electrode modification with polymeric reagents

HD Abruña - Electroresponsive molecular and polymeric systems, 2021 - taylorfrancis.com
The deliberate control of reactivity at the electrode/solution interface represents one of the
primary objectives of electrochemical research. Such control, if possible, would profoundly …

[引用][C] Selective electrocatalytic reduction of hexachloroacetone on a viologen polymer modified electrode in aqueous media

L Coche, JC Moutet - Journal of electroanalytical chemistry and interfacial …, 1988 - Elsevier
Electrocatalysis is one of the leading ideas underlying the development of modified
electrodes [l]. We have previously shown that platinum and carbon electrodes coated with …