Magnetic Anisotropy of Tetrahedral CoII Single-Ion Magnets: Solid-State Effects
S Sottini, G Poneti, S Ciattini, N Levesanos… - Inorganic …, 2016 - ACS Publications
This study reports the static and dynamic magnetic characterization of two mononuclear
tetrahedral CoII complexes,[Co {iPr2P (E) NP (E) iPr2} 2], where E= S (CoS 4) and Se (CoSe …
tetrahedral CoII complexes,[Co {iPr2P (E) NP (E) iPr2} 2], where E= S (CoS 4) and Se (CoSe …
Magnetic Anisotropy in CoIIX4 (X=O, S, Se) Single‐Ion Magnets: Role of Structural Distortions versus Heavy Atom Effect
Mononuclear four coordinate CoII complexes have drawn a great deal of attention as they
often exhibit excellent single‐ion magnet (SIM) properties. Among the reported complexes …
often exhibit excellent single‐ion magnet (SIM) properties. Among the reported complexes …
Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co {(OPPh 2)(EPPh 2) N} 2], E= S, Se, explored by experimental and …
E Ferentinos, D Tzeli, S Sottini, EJJ Groenen… - Dalton …, 2023 - pubs.rsc.org
During the last few years, a large number of mononuclear Co (II) complexes of various
coordination geometries have been explored as potential single ion magnets (SIMs). In the …
coordination geometries have been explored as potential single ion magnets (SIMs). In the …
Multi-technique experimental benchmarking of the local magnetic anisotropy of a cobalt (II) single-ion magnet
A comprehensive understanding of the ligand field and its influence on the degeneracy and
population of d-orbitals in a specific coordination environment are crucial for the rational …
population of d-orbitals in a specific coordination environment are crucial for the rational …
Single-Ion Magnet Et4N[CoII(hfac)3] with Nonuniaxial Anisotropy: Synthesis, Experimental Characterization, and Theoretical Modeling
In this article we report the synthesis and structure of the new Co (II) complex Et4N [CoII
(hfac) 3](I)(hfac= hexafluoroacetylacetonate) exhibiting single-ion magnet (SIM) behavior …
(hfac) 3](I)(hfac= hexafluoroacetylacetonate) exhibiting single-ion magnet (SIM) behavior …
Role of Halide Ions in the Nature of the Magnetic Anisotropy in Tetrahedral CoII Complexes
A series of mononuclear tetrahedral CoII complexes with a general molecular formula
[CoL2X2][L= thiourea and X= Cl (1), Br (2) and I (3)] were synthesized and their structures …
[CoL2X2][L= thiourea and X= Cl (1), Br (2) and I (3)] were synthesized and their structures …
Tuning the coordination geometry and magnetic relaxation of Co (II) single-ion magnets by varying the ligand substitutions
G Peng, YF Qian, ZW Wang, Y Chen… - Crystal Growth & …, 2021 - ACS Publications
Three mononuclear Co (II) complexes with the formulas of [Co (L1) 2](1),[Co (L2) 2 (CH3OH)
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …
Zero-Field SMM Behavior Triggered by Magnetic Exchange Interactions and a Collinear Arrangement of Local Anisotropy Axes in a Linear Co3II Complex
A Zabala-Lekuona, A Landart-Gereka… - Inorganic …, 2023 - ACS Publications
A new linear trinuclear Co (II) 3 complex with a formula of [{Co (μ-L)} 2Co] has been
prepared by self-assembly of Co (II) ions and the N3O3-tripodal Schiff base ligand H3L …
prepared by self-assembly of Co (II) ions and the N3O3-tripodal Schiff base ligand H3L …
Slow magnetic relaxation triggered by a structural phase transition in long-chain-alkylated cobalt (II) single-ion magnets
F Kobayashi, R Ohtani, M Nakamura… - Inorganic …, 2019 - ACS Publications
The behavior of single-ion magnets (SIMs) that reflects large distortions of their coordination
environments caused by the packing of long alkyl chains for two Co (II) complexes of the …
environments caused by the packing of long alkyl chains for two Co (II) complexes of the …