Palladium-catalyzed C–N bond formation via direct C–H bond functionalization. Recent developments in heterocyclic synthesis

EM Beccalli, G Broggini, A Fasana… - Journal of Organometallic …, 2011 - Elsevier
The formation of carbon–nitrogen bonds by reaction between a nitrogen atom and an
unactivated carbon–hydrogen bond is a highly atom-economical process that attracted the …

Palladium-Catalyzed C–H Amination of C(sp2) and C(sp3)–H Bonds: Mechanism and Scope for N-Based Molecule Synthesis

YN Timsina, BF Gupton, KC Ellis - ACS Catalysis, 2018 - ACS Publications
Nitrogen-containing compounds are the most common structural architectures in drug
candidates, natural and biological products, and small-molecule therapeutics. Within the …

Recent developments in the preparation of N-heterocycles using Pd-catalysed C–H activation

TM Shaikh, FE Hong - Journal of Organometallic Chemistry, 2016 - Elsevier
The direct and selective activation of C–H bonds for the synthesis of N-heterocycles (C–N
bonds) is an important area in modern synthetic chemistry due to its wide application in both …

Modern palladium-catalyzed transformations involving C–H activation and subsequent annulation

RS Thombal, PYM Rubio, D Lee, D Maiti, YR Lee - ACS Catalysis, 2022 - ACS Publications
The metal-catalyzed “cascade C–H activation/annulation” is a highly promising approach to
the construction of aromatic and heteroaromatic compounds. In this context, Pd-complexes …

Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation

CL Sun, BJ Li, ZJ Shi - Chemical communications, 2010 - pubs.rsc.org
Direct selective palladium catalyzed C–H functionalization has become a highly attractive
strategy in organic synthesis and represents a highly desirable goal. Compared with cross …

Palladium (II)‐catalyzed C H activation/C C cross‐coupling reactions: versatility and practicality

X Chen, KM Engle, DH Wang… - Angewandte Chemie …, 2009 - Wiley Online Library
Pick your Pd partners: A number of catalytic systems have been developed for palladium‐
catalyzed C H activation/C C bond formation. Recent studies concerning the palladium …

Palladium-catalyzed ligand-directed C− H functionalization reactions

TW Lyons, MS Sanford - Chemical reviews, 2010 - ACS Publications
The development of methods for the direct conversion of carbonshydrogen bonds into
carbon-oxygen, carbon-halogen, carbon-nitrogen, carbon-sulfur, and carbon-carbon bonds …

Ring Construction by Palladium(0)-Catalyzed C(sp3)–H Activation

O Baudoin - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus The catalytic activation and functionalization of unactivated C (sp3)–H bonds of
alkyl groups has undergone intense development in recent years. In particular, a variety of …

[引用][C] Competitive processes in palladium-catalyzed C C bond formation

M Catellani, GP Chiusoli - Journal of Organometallic Chemistry, 1982 - Elsevier
Prm communication COMPETITIVE PROCESSES IN PALLADIUM-CATALYZED CC BOND
FORMATION A palladium-carbon bond, stable towards hydrog Page 1 c21 Journal of …

Easily Accessible Auxiliary for Palladium‐Catalyzed Intramolecular Amination of C(sp2)H and C(sp3)H Bonds at δ‐ and ε‐Positions

C Wang, C Chen, J Zhang, J Han, Q Wang… - Angewandte …, 2014 - Wiley Online Library
An easily synthesized and accessible N, O‐bidentate auxiliary has been developed for
selective C H activation under palladium catalysis. The novel auxiliary showed its first …