Hard X‐ray spectroscopic nano‐imaging of hierarchical functional materials at work

JC Andrews, BM Weckhuysen - ChemPhysChem, 2013 - Wiley Online Library
Heterogeneous catalysts often consist of an active metal (oxide) in close contact with a
support material and various promoter elements. Although macroscopic properties, such as …

Hard and soft X-ray microscopy and tomography in catalysis: bridging the different time and length scales

JD Grunwaldt, CG Schroer - Chemical Society Reviews, 2010 - pubs.rsc.org
X-Ray microscopic techniques are excellent and presently emerging techniques for
chemical imaging of heterogeneous catalysts. Spatially resolved studies in heterogeneous …

[PDF][PDF] A cell design for correlative hard X-ray nanoprobe and electron microscopy studies of catalysts under in situ conditions

JE Parker, M Gomez-Gonzalez… - Journal of …, 2022 - journals.iucr.org
To improve the understanding of catalysts, and ultimately the ability to design better
materials, it is crucial to study them during their catalytic active states. Using in situ or …

X-ray spectroscopy for chemical and energy sciences: the case of heterogeneous catalysis

AI Frenkel, JA van Bokhoven - Journal of synchrotron radiation, 2014 - journals.iucr.org
Heterogeneous catalysis is the enabling technology for much of the current and future
processes relevant for energy conversion and chemicals synthesis. The development of new …

New Dimensions in Catalysis Research with Hard X‐Ray Tomography

S Das, R Pashminehazar, S Sharma… - Chemie Ingenieur …, 2022 - Wiley Online Library
The structure and function of solid catalysts are inseparably linked at length scales from nm
to cm and beyond. Hard X‐ray tomography offers unique potential for spatially‐resolved …

Catalysts at work: From integral to spatially resolved X-ray absorption spectroscopy

JD Grunwaldt, B Kimmerle, A Baiker, P Boye… - Catalysis Today, 2009 - Elsevier
Spectroscopic studies on heterogeneous catalysts have mostly been done in an integral
mode. However, in many cases spatial variations in catalyst structure can occur, eg during …

Chemical imaging of catalytic solids with synchrotron radiation

AM Beale, SDM Jacques… - Chemical Society Reviews, 2010 - pubs.rsc.org
Heterogeneous catalysis is a term normally used to describe a group of catalytic processes,
yet it could equally be employed to describe the catalytic solid itself. A better understanding …

Challenges and opportunities for applications of advanced X-ray spectroscopy in catalysis research

GE Cutsail III, S DeBeer - ACS Catalysis, 2022 - ACS Publications
X-ray spectroscopy has had a significant and continually growing impact on catalysis
research for nearly 50 years. In particular, the ability to obtain element selective electronic …

Nanoscale chemical imaging with structured X-ray illumination

J Li, S Chen, D Ratner, T Blu… - Proceedings of the …, 2023 - National Acad Sciences
High-resolution imaging with compositional and chemical sensitivity is crucial for a wide
range of scientific and engineering disciplines. Although synchrotron X-ray imaging through …

Nanoscale chemical imaging of a working catalyst by scanning transmission X-ray microscopy

E de Smit, I Swart, JF Creemer, GH Hoveling, MK Gilles… - Nature, 2008 - nature.com
The modern chemical industry uses heterogeneous catalysts in almost every production
process. They commonly consist of nanometre-size active components (typically metals or …