Fine-tuning the activity of metal–organic framework-supported cobalt catalysts for the oxidative dehydrogenation of propane
Few-atom cobalt-oxide clusters, when dispersed on a Zr-based metal–organic framework
(MOF) NU-1000, have been shown to be active for the oxidative dehydrogenation (ODH) of …
(MOF) NU-1000, have been shown to be active for the oxidative dehydrogenation (ODH) of …
Metal–organic framework supported cobalt catalysts for the oxidative dehydrogenation of propane at low temperature
Zr-based metal–organic frameworks (MOFs) have been shown to be excellent catalyst
supports in heterogeneous catalysis due to their exceptional stability. Additionally, their …
supports in heterogeneous catalysis due to their exceptional stability. Additionally, their …
Computational Predictions and Experimental Validation of Alkane Oxidative Dehydrogenation by Fe2M MOF Nodes
The modular structure of metal–organic frameworks (MOFs) makes them promising
platforms for catalyst design and for elucidating structure/performance relationships in …
platforms for catalyst design and for elucidating structure/performance relationships in …
Site-directed synthesis of cobalt oxide clusters in a metal–organic framework
Direct control over structure and location of catalytic species deposited on amorphous
supports represents a formidable challenge in heterogeneous catalysis. In contrast, a …
supports represents a formidable challenge in heterogeneous catalysis. In contrast, a …
Influence of First and Second Coordination Environment on Structural Fe (II) Sites in MIL-101 for C–H Bond Activation in Methane
Divalent iron sites in tri-iron oxo-centered metal nodes in metal–organic frameworks (MOFs)
catalyze light alkane oxidation. The first two steps of the reaction sequence, which are also …
catalyze light alkane oxidation. The first two steps of the reaction sequence, which are also …
Structural Evolution of Iron-Loaded Metal–Organic Framework Catalysts for Continuous Gas-Phase Oxidation of Methane to Methanol
B Rungtaweevoranit, AM Abdel-Mageed… - … Applied Materials & …, 2023 - ACS Publications
Catalytic partial oxidation of methane presents a promising route to convert the abundant but
environmentally undesired methane gas to liquid methanol with applications as an energy …
environmentally undesired methane gas to liquid methanol with applications as an energy …
Kinetic Probes of the Origin of Activity in MOF-Based C–H Oxidation Catalysis
The development of homogeneous catalysis is enabled by the availability of a rich toolkit of
kinetics experiments, such as the Hg-drop test, that differentiate catalytic activity at ligand …
kinetics experiments, such as the Hg-drop test, that differentiate catalytic activity at ligand …
[PDF][PDF] Structure and function tailored metal-organic frameworks for heterogeneous catalysis
The unlimited combination of building units, tunable structures, and facilitation of tailoring
active sites endows metal-organic frameworks (MOFs) with high activity as heterogeneous …
active sites endows metal-organic frameworks (MOFs) with high activity as heterogeneous …
Beyond radical rebound: Methane oxidation to methanol catalyzed by iron species in metal–organic framework nodes
Recent work has exploited the ability of metal–organic frameworks (MOFs) to isolate Fe sites
that mimic the structures of sites in enzymes that catalyze selective oxidations at low …
that mimic the structures of sites in enzymes that catalyze selective oxidations at low …
Quantum chemical characterization of structural single Fe (II) sites in MIL-type metal–organic frameworks for the oxidation of methane to methanol and ethane to …
Single non-heme Fe (II) ions present as structural moieties in several metal–organic
frameworks (eg, MIL-100, MIL-101, and MIL-808, where MIL indicates Materials of Institute …
frameworks (eg, MIL-100, MIL-101, and MIL-808, where MIL indicates Materials of Institute …