Electrochemical Rectification Using Mixed Monolayers of Redox-Active Ferrocenyl Dendrimers and n-Alkanethiols

SK Oh, LA Baker, RM Crooks - Langmuir, 2002 - ACS Publications
A strategy for constructing a dendrimer-based electrochemical current rectifier that permits
current flow in only one direction is described. This approach is based on the insulating …

Electronic communication between immobilized ferrocenyl-terminated dendrimers

A Wang, C Ornelas, D Astruc… - Journal of the American …, 2009 - ACS Publications
Redox-active ferrocenyl-terminated dendrimers have been used to build robust and active
interfaces in which the inherent properties of the dendrimers are preserved. The procedure …

Redox-active ferrocenyl dendrimers: thermodynamics and kinetics of adsorption, in-situ electrochemical quartz crystal microbalance study of the redox process and …

K Takada, DJ Díaz, HD Abruña… - Journal of the …, 1997 - ACS Publications
The thermodynamics and kinetics of adsorption of the redox-active dendrimers
diaminobutane-dend-(NHCOFc) 8,(dendrimer-Fc8), diaminobutane-dend-(NHCOFc) …

Synthesis and electrochemistry of octamethylferrocenyl-functionalized dendrimers

M Zamora, S Herrero, J Losada, I Cuadrado… - …, 2007 - ACS Publications
New octamethylferrocenyl dendritic macromolecules are reported. The condensation
reaction of octamethylferrocenyl aldehyde (1) with dendritic polyamines DAB-dend-(NH2) x …

Electrochemical rectification at a monolayer-modified electrode

KS Alleman, K Weber, SE Creager - The Journal of Physical …, 1996 - ACS Publications
An electrochemical current rectifier based on a ferrocene-monolayer-modified electrode in
contact with an electrolyte solution containing sodium hexacyanoferrate (II)(sodium …

Ferrocenyl dendrimers: multi-electron redox reagents and their applications

D Astruc - New Journal of Chemistry, 2011 - pubs.rsc.org
In this Perspective article, the assembly of ferrocenyl dendrimers, from small to giant sizes, is
shown to provide a variety of key properties resulting from multi-electron-transfer …

Redox-active ferrocenyl dendrimers and polymers in solution and immobilised on electrode surfaces

CM Casado, I Cuadrado, M Morán, B Alonso… - Coordination chemistry …, 1999 - Elsevier
This article reviews the electrochemical properties of different families of redox-active silicon-
and amine-based ferrocenyl polymers and dendrimers prepared in our laboratory over the …

Preparation and characterization of dendrimer monolayers and dendrimer− alkanethiol mixed monolayers adsorbed to gold

H Tokuhisa, M Zhao, LA Baker, VT Phan… - Journal of the …, 1998 - ACS Publications
Single-component monolayers of dendrimers and two-component monolayers consisting of
dendrimers and n-alkanethiols immobilized on Au substrates are described. Single …

Electrochemical impedimetry of electrodeposited poly (propylene imine) dendrimer monolayer

OA Arotiba, JH Owino, PG Baker, EI Iwuoha - Journal of Electroanalytical …, 2010 - Elsevier
Voltammetric and electrochemical impedance spectroscopic (EIS) studies of generation one
poly (propylene imine)(G1 PPI) dendrimer as an electroactive and catalytic nanomaterials …

Tunneling dendrimers. Enhancing charge transport through insulating layer using redox molecular objects

S Lhenry, J Jalkh, YR Leroux, J Ruiz… - Journal of the …, 2014 - ACS Publications
Charge transport through an insulating layer was probed using ferrocenyl-terminated
dendrimers and scanning electrochemical microscopy. Experiments show that the passage …