Total syntheses of (±)-and (−)-stemoamide

PA Jacobi, K Lee - Journal of the American Chemical Society, 2000 - ACS Publications
(±)-Stemoamide (1) was prepared in seven steps beginning with γ-chlorobutryl chloride (20)
and succinimide (15), which were efficiently converted to the key alkyne oxazole 17 on a …

Synthesis of the proposed structures of parvistemoamide and their transformations to stemoamide derivatives

F Cao, W Gao, X Wang, Z Zhang, G Yin, Y Wang… - Organic …, 2021 - ACS Publications
The proposed structures of parvistemoamide have been achieved by macrolactamization,
but none of the characterization data of synthetic samples matched with those of the natural …

Flexible Approach to Stemona Alkaloids: Total Syntheses of (−)-Stemospironine and Three New Diastereoisomeric Analogs

N Bardají, F Sánchez-Izquierdo, R Alibés, J Font… - Organic …, 2012 - ACS Publications
Total syntheses of (−)-stemospironine and three new diastereoisomeric analogs have been
completed through a flexible strategy devised for Stemona alkaloids. The azabicycle 7 is the …

Stemona Alkaloids: Biosynthesis, Classification, and Biogenetic Relationships

FP Wang, QH Chen - Natural Product Communications, 2014 - journals.sagepub.com
Stemona alkaloids form a unique class, which can be attributed to hemiterpenoid pyrrolidine-
and monoterpenoid pyrrolidine-class alkaloids originated from L-ornithine and glutamic …

Model support studies toward the total synthesis of the stemona alkaloid stemocurtisine

SR Shengule, AC Willis, SG Pyne - Tetrahedron, 2013 - Elsevier
Herein we report the results of a furan-based approach toward the synthesis of the Stemona
alkaloid, stemocurtisine 1 via the linearly fused tricyclic intermediate 3, representing the key …

Structurally Diverse Matrine‐Based Alkaloids with Anti‐inflammatory Effects from Sophora alopecuroides

D Luo, NH Chen, WZ Wang, JH Zhang… - Chinese Journal of …, 2021 - Wiley Online Library
Main observation and conclusion A phytochemical investigation on the seeds of Sophora
alopecuroides led to obtaining fourteen structurally diverse matrine‐based alkaloids (1 …

Total synthesis of (±)-stemoamide

PA Jacobi, K Lee - Journal of the American Chemical Society, 1997 - ACS Publications
Stemoamide (1) is a member of the stemona class of alkaloids that was isolated in 1992
from the roots of Stemona tuberosa (Figure 1). 1a Alkaloids of this genus typically …

Recent advances in the transformations of different types of Stemona alkaloids

T Shi, X Wang, J Chen, F Cao, G Yin… - Organic Chemistry …, 2022 - pubs.rsc.org
In recent years, researches on the total syntheses of Stemona alkaloids with different 5/7
bicyclic systems have attracted increasing attention, and the development momentum in this …

The chemistry of Stemona alkaloids: An update

RA Pilli, GB Rosso, MCF de Oliveira - Natural Product Reports, 2010 - pubs.rsc.org
Covering: 1999 to August 2009. Previous review: Nat. Prod. Rep., 2000, 17, 117 In the
review period, 97 new representatives of Stemona alkaloids were described, bringing the …

Strategies for the synthesis of Stemona alkaloids: an update

WJ Olivier, JS Henneveld, JA Smith… - Natural product …, 2022 - pubs.rsc.org
Covering: 2009 to 2022 The Stemona alkaloids, which are found in plant species from the
family Stemonaceae, represent a tremendously large and structurally-diverse family of …