Challenges and opportunities for applications of advanced X-ray spectroscopy in catalysis research

GE Cutsail III, S DeBeer - ACS Catalysis, 2022 - ACS Publications
X-ray spectroscopy has had a significant and continually growing impact on catalysis
research for nearly 50 years. In particular, the ability to obtain element selective electronic …

Advanced X-ray absorption and emission spectroscopy: in situ catalytic studies

J Singh, C Lamberti, JA van Bokhoven - Chemical Society Reviews, 2010 - pubs.rsc.org
Knowledge of the structure of catalysts is essential to understand their behavior, which
further facilitates development of an active, selective, and stable catalyst. Determining the …

Applications of synchrotron-based X-ray microprobes

PM Bertsch, DB Hunter - Chemical Reviews, 2001 - ACS Publications
The past decade has witnessed significant advances in technologies related to X-ray
spectroscopic techniques, both as a result of advances in X-ray optics, focusing devices, and …

[HTML][HTML] An improved laboratory-based x-ray absorption fine structure and x-ray emission spectrometer for analytical applications in materials chemistry research

EP Jahrman, WM Holden, AS Ditter… - Review of Scientific …, 2019 - pubs.aip.org
X-ray absorption fine structure (XAFS) and x-ray emission spectroscopy (XES) are advanced
x-ray spectroscopies that impact a wide range of disciplines. However, unlike the majority of …

Bridging the gap between the X-ray absorption spectroscopy and the computational catalysis communities in heterogeneous catalysis: a perspective on the current …

R Rana, FD Vila, AR Kulkarni, SR Bare - ACS Catalysis, 2022 - ACS Publications
X-ray absorption spectroscopy (XAS)[extended X-ray absorption fine structure (EXAFS) and
X-ray absorption near-edge structure (XANES)] is a key technique within the heterogeneous …

Hard X‐ray spectroscopic nano‐imaging of hierarchical functional materials at work

JC Andrews, BM Weckhuysen - ChemPhysChem, 2013 - Wiley Online Library
Heterogeneous catalysts often consist of an active metal (oxide) in close contact with a
support material and various promoter elements. Although macroscopic properties, such as …

New reflections on hard X-ray photon-in/photon-out spectroscopy

S Lafuerza, M Retegan, B Detlefs, R Chatterjee… - Nanoscale, 2020 - pubs.rsc.org
Analysis of the electronic structure and local coordination of an element is an important
aspect in the study of the chemical and physical properties of materials. This is particularly …

HERFD-XAS and valence-to-core-XES: new tools to push the limits in research with hard X-rays?

M Bauer - Physical Chemistry Chemical Physics, 2014 - pubs.rsc.org
In this perspective, the HERFD-XANES (high energy resolution fluorescence detected X-ray
absorption near edge structure) and Kβ2, 5-or V2C-XES (valence-to-core X-ray emission …

Combining synchrotron-based X-ray techniques with vibrational spectroscopies for the in situ study of heterogeneous catalysts: a view from a bridge

MA Newton, W van Beek - Chemical Society Reviews, 2010 - pubs.rsc.org
The advantages, challenges, and future possibilities for combining synchrotron-based X-ray
techniques with vibrational spectroscopies are considered in this critical review. Particular …

The chemical sensitivity of X-ray spectroscopy: high energy resolution XANES versus X-ray emission spectroscopy of substituted ferrocenes

AJ Atkins, M Bauer, CR Jacob - Physical Chemistry Chemical Physics, 2013 - pubs.rsc.org
X-ray spectroscopy at the metal K-edge is an important tool for understanding catalytic
processes and provides insight into the geometric and electronic structures of transition …