Hydrogen oxidation catalysis by a nickel diphosphine complex with pendant tert-butyl amines

JY Yang, S Chen, WG Dougherty, WS Kassel… - Chemical …, 2010 - pubs.rsc.org
A bis-diphosphine nickel complex with tert-butyl functionalized pendant amines [Ni (PCy2Nt-
Bu2) 2] 2+ has been synthesized. It is a highly active electrocatalyst for the oxidation of …

Two pathways for electrocatalytic oxidation of hydrogen by a nickel bis (diphosphine) complex with pendant amines in the second coordination sphere

JY Yang, SE Smith, T Liu, WG Dougherty… - Journal of the …, 2013 - ACS Publications
A nickel bis (diphosphine) complex containing pendant amines in the second coordination
sphere,[Ni (PCy2N t-Bu2) 2](BF4) 2 (PCy2N t-Bu2= 1, 5-di (tert-butyl)-3, 7-dicyclohexyl-1, 5 …

Hydrogen oxidation and production using nickel-based molecular catalysts with positioned proton relays

AD Wilson, RH Newell, MJ McNevin… - Journal of the …, 2006 - ACS Publications
Highly efficient electrocatalysts for both hydrogen evolution and hydrogen oxidation have
been designed, synthesized, and characterized. The catalysts in their resting states are air …

Controlling proton movement: electrocatalytic oxidation of hydrogen by a nickel (II) complex containing proton relays in the second and outer coordination spheres

P Das, MH Ho, M O'Hagan, WJ Shaw, RM Bullock… - Dalton …, 2014 - pubs.rsc.org
A nickel bis (diphosphine) complex containing proton relays in the second and outer
coordination spheres, Ni (PCy2N (CH2) 2OMe) 2,(PCy2N (CH2) 2OMe= 1, 5-di …

Mechanistic Insights into Catalytic H2 Oxidation by Ni Complexes Containing a Diphosphine Ligand with a Positioned Amine Base

JY Yang, RM Bullock, WJ Shaw… - Journal of the …, 2009 - ACS Publications
The mixed-ligand complex [Ni (dppp)(PPh2NBz2)](BF4) 2, 3,(where PPh2NBz2 is 1, 5-
dibenzyl-3, 7-diphenyl-1, 5-diaza-3, 7-diphosphacyclooctane and dppp is 1, 3-bis …

Iron Complexes Bearing Diphosphine Ligands with Positioned Pendant Amines as Electrocatalysts for the Oxidation of H2

T Liu, Q Liao, M O'Hagan, EB Hulley, DL DuBois… - …, 2015 - ACS Publications
The synthesis and spectroscopic characterization of CpC5F4NFe (P t Bu2NBn2) Cl,[3-
Cl](where C5F4N is a tetrafluoropyridyl substituent and P t Bu2NBn2= 1, 5-dibenzyl-3, 7-di …

Molecular electrocatalysts for oxidation of hydrogen using earth-abundant metals: shoving protons around with proton relays

RM Bullock, ML Helm - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Sustainable, carbon-neutral energy is needed to supplant the worldwide
reliance on fossil fuels in order to address the persistent problem of increasing emissions of …

A new catalyst based on a nickel (II) complex of diiminodiphosphine for hydrogen evolution and oxidation

CL Wang, H Yang, J Du, SZ Zhan - International Journal of Hydrogen …, 2021 - Elsevier
Based on that hydrogen energy is widely used in fuel cells, we focus our interests on the
design and research of new complexes that catalyze the reaction in both directions, such as …

New functional cyclic aminomethylphosphine ligands for the construction of catalysts for electrochemical hydrogen transformations

EI Musina, VV Khrizanforova, ID Strelnik… - … A European Journal, 2014 - Wiley Online Library
Eight‐membered cyclic functional bisphosphines, namely 1, 5‐di‐aryl‐3, 7‐di (2‐pyridyl)‐1,
5‐diaza‐3, 7‐diphosphacyclooctanes (aryl= 2‐pyridyl, m‐tolyl, p‐tolyl, diphenylmethyl …

[HTML][HTML] The role of pendant bases in molecular catalysts for H2 oxidation and production

MR DuBois, DL DuBois - Comptes …, 2008 - comptes-rendus.academie-sciences …
Résumé The paper presents a review of recent studies of complexes of Ni (II) and Fe (II)
coordinated by diphosphine ligands with amine bases incorporated into the ligand chelate …