… oxygen base, on account of the very different base strengths of secondary aliphatic amines
and … which one is the more basic. Likewise, even the simplest carboxylic amide features two …

… (PA), basicities (GB), and solvation energies for the neutral and protonated aliphatic amines
… (GB) changes for deprotonation of the protonated amine species in the gas phase are in …

… the basic strength on bond angles seems to be invalid. Because the basicity of cyclic amines
is … due to complicated solvation effects. On the other hand, the gas-phase proton affinities of …

… amines contrasting with these results. We have first selected a diversified sample of 69 amines
… We may wonder if the agreement would be improved by taking account of solvation effects…

… for the contribution of amine basicity. In fact, … amine basicity isless affected by the diluent.
The latter may still contribute through solvation of the amine—acid complex or through solvation …

… amines (anilines) – bases where the basicity center is conjugated with an aromatic ring in the
neutral form – as well as the aromatic heterocycles are amongst the least basic… on solvation…

… The pKa of an amine does not, however, … amine and the solvation of both the base and its
cation. Methods of measuring the electron availability at the nitrogen atom without the solvation …

… amine properties and reaction enthalpy with CO 2 is still limited. Steric hindrance and amine
basicity have … Given the largely aqueous environment of amine solvents, the CO 2 solvation …

… basicity is recognized as playing a major role in solvation and is included, through empirical
basicity … is 0.86 and removing all of the amines, anilines and pyridines from the correlation …

… If we construct a molecular model of the DEMT-HOC4H9-(er( complex, we find a … kH, and
the lackof sensitivity to the base strength of the amine are entirely consistent with data in Tables …