… model hydrogen bonds between the solute and the solvent … , we investigate solvent effects
on the optical rotations using … ) and explicit solvent effects on the optical rotations. The CAM-…

… rotation about a conjugated C−N bond, to see whether a similar pattern would emerge in the
solvent effects … to C−N bond rotation in DMAAN in a variety of solvents would compare to the …

… From this perspective, the lack of a solvent effect on the rate of bond rotation in carbamates
… quadratic equation predicts that the solvent effect on bond rotation should be somewhat less …

… solvent effects on the barrier to C−N bond rotation is of some importance. This barrier has
been investigated both experimentally and theoretically. We have determined the activation …

… absolute magnitude of the solvent effects by about 1.5 kcal/… methodology, 27 predicting a
solvent effect of 1.0 kcal/mol in … solvent effects on rotation about the conjugated C−N bond of …

… solvents' capabilities to give and accept hydrogen bonds from MBA. In this study, the specific
rotation was fit using the solvent … −Taft solvent parameters, is the observed specific rotation, …

… Very similar solvent effects on equilibrium constants and rotation barriers are found … rotation
barriers in alcohols 3 and 9 clearly show that solvent hydrogen bonding has little or no effect …

… the above reaction system in different solvents. There is some … Theoretical investigation of
solvent effect on the structure … and to study the effects of different solvents on the stability by …

… polar solvents the rotation about the central double bond is … point out the importance of
solvent effects on the excited-state … in different solvents, which reflects the importance of solvent …

… solvent effects on the conformationalequilibrium of 1,2-dichloroethaneand furfural are in good
agreement with experiments. The rotational barriers … such as hydrogen bonding and donor-…