Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co {(OPPh 2)(EPPh 2) N} 2], E= S, Se, explored by experimental and …

E Ferentinos, D Tzeli, S Sottini, EJJ Groenen… - Dalton …, 2023 - pubs.rsc.org
During the last few years, a large number of mononuclear Co(II) complexes of various
coordination geometries have been explored as potential single ion magnets (SIMs). In the work …

Single-chain magnets constructed by using the strict orthogonality of easy-planes: use of structural flexibility to control the magnetic properties

T Kajiwara, H Tanaka, M Nakano, S Takaishi… - Inorganic …, 2010 - ACS Publications
… of Fe II ions and the magnetic interaction between Fe(II)−Fe(III) ions, the … structure. In the
other words, the magnetic properties of this system respond to changes in the chain structure. …

Structural versatility driven by the flexible di (4-pyridyl) sulfide ligand: From cobalt (II) single-ion magnets to sheet-like copper (II) weak antiferromagnets

NV Reis, MV Marinho, TRG Simoes, KC Metz, RCA Vaz… - Polyhedron, 2019 - Elsevier
… Crystal structures of 1–3 were determined using single-crystal X-ray diffraction. Crystal structure
of … behavior and behaves as a single-ion magnet with an effective energy barrier for the …

Reversible tuning of luminescence and magnetism in a structurally flexible erbium–anilato MOF

N Monni, JJ Baldoví, V García-López, M Oggianu… - Chemical …, 2022 - pubs.rsc.org
ion magnetsions into a 3D framework affording the so-called SIM-MOF. Among the organic
linkers which can either act as a powerful antenna or isolate magnetically the Ln III metal ions

Porous anionic, cationic, and neutral metal-carboxylate frameworks constructed from flexible tetrapodal ligands: syntheses, structures, ion-exchanges, and magnetic …

TF Liu, J Lü, C Tian, M Cao, Z Lin, R Cao - Inorganic Chemistry, 2011 - ACS Publications
… adapt their structural features, pore sizes, and framework charges to the metal ions and
temperature … In this paper we report the solvothermal syntheses, structural characterizations, ion-…

A flexible coordination polymer crystal providing reversible structural and magnetic conversions

W Kaneko, M Ohba, S Kitagawa - Journal of the American …, 2007 - ACS Publications
… they naturally provide structural flexibility as an inherent … the CP magnets' (CPMs') framework
and provide structural and … Mn II ions to form a 2D corrugated sheet structure on the ab …

Oligonuclear complexes as tectons in crystal engineering: structural diversity and magnetic properties

M Andruh - Chemical communications, 2007 - pubs.rsc.org
… two or more metal ions confers on the node a higher geometrical flexibility. … ions are strongly
anisotropic (as a prerequisite for obtaining single molecule magnets or single chain magnets

The Rule Rather than the Exception: Structural Flexibility of [Ni(cyclam)]2+-Based Cyano-Bridged Magnetic Networks

B Nowicka, M Reczynski, M Bałanda, M Fitta… - Crystal Growth & …, 2016 - ACS Publications
… The molecular magnetism was at that time an emerging field and the impact of subtle structural
… Ni2 ion in all structures occupies an inversion center, while the symmetry of Ni1 and Ni3 …

Structural diversities and magnetic properties of azide-containing coordination polymers based on flexible tetra-pyridinate ligands

F Yu, M Xiang, A Li, Y Zhang, B Li - CrystEngComm, 2015 - pubs.rsc.org
… -ion anisotropy of Ni(II) or possible structural phase … magnets, and the combination of
flexible tetra-pyridinate coligands and azido could result in variable three-dimensional structures, …

Series of anion-directed lanthanide-rigid-flexible frameworks: syntheses, structures, luminescence and magnetic properties

X Feng, LY Wang, JS Zhao, JG Wang, NS Weng… - …, 2010 - pubs.rsc.org
structures 4 and various properties such as catalysis, luminescence, and atypical magnetism
… , such as the chemical structure of the ligand, the inorganic counter ion, the pH values and …