… for the preparation of aryl-phosphorus compounds. Presented herein is a competent process
for the synthesis of aryl-phosphonates, -phosphinates, and -phosphine oxides by making …

… of changing the electronics of aryl phosphonates were explored. Across a diverse range
of electronic and steric influences, yields of phosphine oxides ranged from good to excellent (…

A novel palladium-catalyzed synthesis of arylphosphonates from arenediazonium tetrafluoroborates
and triethylphosphite or diethylphosphite is presented. The reaction tolerates useful …

… Reduction of phosphine oxides is the final traditional method of phosphine synthesis. It has
been … It was found in the 1980’s that arylphosphonates, arylphosphinates and arylphosphine …

… The gross reactivity order of the arylphosphonates depending on the alkyl group of the ester
… reacting amides, paraformaldehyde and secondary phosphine oxides using the amide in a …

… H-phosphine oxides to alkynes, including acetylene gas, and also5d examined the tBuOK-catalyzed
reductive addition to terminal alkynes for the synthesis of -arylphosphine oxides. …

… phosphine oxides to phosphines using a wide range of reagents and conditions. Thus, reduction
is typically not a difficult step in phosphine synthesis … halides to form aryl phosphonates. …

… used for the synthesis of tertiary phosphine oxides by a direct P-arylation of secondary
phosphines, … methodology was successfully used in the synthesis of 14 triarylphosphine oxides. …

… Similarly to phosphinates, phosphinic amides may also be synthesized by the Atherton -
Todd reaction using secondary phosphine oxides and amines as the nucleophiles [119, 120]. …

… and diarylphosphine oxides (13i,k-m), we found that the phosphinoylation with bis(2-methylphenyl)phosphine
oxide (13l) and bis(3,5- dimethylphenyl)phosphine oxide (13m) was …