… trimethylene carbonate (TMC) from a low nucleophilic organic superbase of phosphazene
(t-… was carefully studied to prepare poly(trimethylene carbonate) (PTMC) which is one of the …

… 4) while the Odelius group utilized a phosphazene base (5). In order to avoid the issue of
remnant metal impurities in polymers, we sought an organo-catalyst for polymerizing α-ArTMC. …

… The regioselective organocatalytic ring-opening polymerization (ROP) of a 6-membered
cyclic carbonate, rac-1-methyl trimethylene carbonate, was studied using phosphazene base (t-…

… We have investigated the efficacy of several organocatalysts for the depolymerization of
PTMC as a base material for future sustainable materials. A phosphazene base P 2 -t-Bu …

… for the organocatalytic ROP, we focused on cyclic carbonates and … carbonates, such as
trimethylene carbonate (TMC), has been studied using nucleophilic and basic organocatalysts…

… of trimethylene carbonate (TMC), some organocatalysts have been shown to lead to well
defined poly(trimethylene carbonate… of a cyclic carbonate by a phosphazene. Remarkably, such …

… )s and/or functional six-membered cyclic carbonate monomers. This transformation is …
organocatalytic oxetane/CO 2 coupling procedure that enables the selection of cyclic carbonate …

… ), followed by the eminently important class of phosphazene bases (Section 4.3) and by N-…
demonstrated that organocatalytic synthesis of polycarbonates from trimethylene carbonate (…

… to further development of ionic pairs as organocatalysts. A combination of benzoic acid and
… (14−16) It should be noted that before this work most of the organocatalysts suffered from a …

… phosphazene-based carboxylic acids presents an increased activity when the interaction
between the carboxylate anion and its protonated phosphazene … and trimethylene carbonate …