Molecular catalysts with diphosphine ligands containing pendant amines

ES Wiedner, AM Appel, S Raugei, WJ Shaw… - Chemical …, 2022 - ACS Publications
… of a tertiary amine, while the control complex has a CH 2 in that position. This type of
diphosphine containing one pendant amine is referred to in this article as a PNP ligand, using the …

[HTML][HTML] The role of pendant bases in molecular catalysts for H2 oxidation and production

MR DuBois, DL DuBois - Comptes …, 2008 - comptes-rendus.academie-sciences …
… Ni(II) and Fe(II) coordinated by diphosphine ligands with amine bases incorporated into the
… the diphosphine ligands that we have studied. These include ligands with pendant terminal …

High catalytic rates for hydrogen production using nickel electrocatalysts with seven-membered cyclic diphosphine ligands containing one pendant amine

MP Stewart, MH Ho, S Wiese… - Journal of the …, 2013 - ACS Publications
… of related nickel bis(diphosphine) catalysts that contain ligands that are structurally modified…
a modified nickel catalyst containing two seven-membered cyclic diphosphine ligands 7P Ph …

Catalytic oxidation of alcohol via nickel phosphine complexes with pendant amines

CJ Weiss, P Das, DL Miller, ML Helm, AM Appel - Acs Catalysis, 2014 - ACS Publications
… Nickel complexes were prepared with diphosphine ligands that contain pendant amines, …
influences the catalytic activity. For the oxidation of diphenylmethanol, the catalytic rates were …

Mechanistic Insights into Catalytic H2 Oxidation by Ni Complexes Containing a Diphosphine Ligand with a Positioned Amine Base

JY Yang, RM Bullock, WJ Shaw… - Journal of the …, 2009 - ACS Publications
containing diphosphine ligands with amine bases (or proton relays) in the second coordination
sphere exhibit much higher catalytic … ) 2 each contain two amine bases positioned within …

Hydrogen oxidation catalysis by a nickel diphosphine complex with pendant tert-butyl amines

JY Yang, S Chen, WG Dougherty, WS Kassel… - Chemical …, 2010 - pubs.rsc.org
… P R 2 N R′ 2 denotes cyclic diphosphine ligands that incorporate an amine base in each
ligand chelate ring, where R and R′ are substituents on the phosphorus and nitrogen atoms, …

Synthesis, structures, and reactions of manganese complexes containing diphosphine ligands with pendant amines

KD Welch, WG Dougherty, WS Kassel… - …, 2010 - ACS Publications
… rates in Ni electrocatalysts for oxidation of H 2 compared to catalysts with just one … For
comparison to our Mn complexes with diphosphines containing pendant amines, the manganese …

Molecular cobalt complexes with pendant amines for selective electrocatalytic reduction of carbon dioxide to formic acid

S Roy, B Sharma, J Pécaut, P Simon… - Journal of the …, 2017 - ACS Publications
… R′ 2 ligands with … phosphine ligand and the most basic amine functions performs best
among the series, with turnover frequency >1000 s –1 . State-of-the-art benchmarking of catalytic

Two pathways for electrocatalytic oxidation of hydrogen by a nickel bis (diphosphine) complex with pendant amines in the second coordination sphere

JY Yang, SE Smith, T Liu, WG Dougherty… - Journal of the …, 2013 - ACS Publications
catalysts based on a nickel bis(diphosphine) framework [Ni(P R 2 N R′ 2 ) 2 ] 2+ , where P
R 2 N R′ 2 is an eight-membered diphosphine ligand with two pendant amines, … amines are …

Reduction of oxygen catalyzed by nickel diphosphine complexes with positioned pendant amines

JY Yang, RM Bullock, WG Dougherty, WS Kassel… - Dalton …, 2010 - pubs.rsc.org
… nickel complexes and our studies of the role of the pendant bases in the catalytic reactions.
… The latter complex, with no pendant amines, was chosen for comparisons in this work …