A biocatalytic hydrogenation of carboxylic acids
Y Ni, PL Hagedoorn, JH Xu, IWCE Arends… - Chemical …, 2012 - pubs.rsc.org
Chemical Communications, 2012•pubs.rsc.org
The hyperthermophile Pyrococcus furiosus catalyses the hydrogenation of a broad range of
carboxylic acids selectively to the corresponding primary alcohols. Other functional groups
such as isolated CC-double bonds are not touched. The chemoselectivity of the carboxylate
reduction may be directed towards aldehydes by simple medium engineering.
carboxylic acids selectively to the corresponding primary alcohols. Other functional groups
such as isolated CC-double bonds are not touched. The chemoselectivity of the carboxylate
reduction may be directed towards aldehydes by simple medium engineering.
The hyperthermophile Pyrococcus furiosus catalyses the hydrogenation of a broad range of carboxylic acids selectively to the corresponding primary alcohols. Other functional groups such as isolated CC-double bonds are not touched. The chemoselectivity of the carboxylate reduction may be directed towards aldehydes by simple medium engineering.
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