A flexoelectricity-enabled ultrahigh piezoelectric effect of a polymeric composite foam as a strain-gradient electric generator

D Yan, J Wang, J Xiang, Y Xing, LH Shao - Science Advances, 2023 - science.org
D Yan, J Wang, J Xiang, Y Xing, LH Shao
Science Advances, 2023science.org
All dielectric materials including ceramics, semiconductors, biomaterials, and polymers have
the property of flexoelectricity, which opens a fertile avenue to sensing, actuation, and
energy harvesting by a broad range of materials. However, the flexoelectricity of solids is
weak at the macroscale. Here, we achieve an ultrahigh flexoelectric effect via a composite
foam based on PDMS and CCTO nanoparticles. The mass-and deformability-specific
flexoelectricity of the foam exceeds 10,000 times that of the solid matrix under compression …
All dielectric materials including ceramics, semiconductors, biomaterials, and polymers have the property of flexoelectricity, which opens a fertile avenue to sensing, actuation, and energy harvesting by a broad range of materials. However, the flexoelectricity of solids is weak at the macroscale. Here, we achieve an ultrahigh flexoelectric effect via a composite foam based on PDMS and CCTO nanoparticles. The mass- and deformability-specific flexoelectricity of the foam exceeds 10,000 times that of the solid matrix under compression, yielding a density-specific equivalent piezoelectric coefficient 120 times that of PZT. The flexoelectricity output remains stable in 1,000,000 deformation cycles, and a portable sample can power LEDs and charge mobile phones and Bluetooth headsets. Our work provides a route to exploiting flexible and light-weight materials with highly sensitive omnidirectional electromechanical coupling that have applications in sensing, actuation, and scalable energy harvesting.
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