A geometric representation of nuclear modulation effects: The effects of high electron spin multiplicity on the electron spin echo envelope modulation spectra of Mn2+ …
A theoretical treatment is presented for the analysis of ESEEM spectra of 1= 1/2 nuclei
coupled to an electron spin of high multiplicity, with specific attention to the case of S= 5/2.
This treatment is shown to account for the observed spectral behavior of 15N and 31p nuclei
coupled to Mn2+ in a GDP complex with the protein N-ras p21. The treatment involves the
decomposition of the multilevel electron spin system into a set of noninteracting two level
systems, an approximation that is valid when the dispersed EPR spectral width is large …
coupled to an electron spin of high multiplicity, with specific attention to the case of S= 5/2.
This treatment is shown to account for the observed spectral behavior of 15N and 31p nuclei
coupled to Mn2+ in a GDP complex with the protein N-ras p21. The treatment involves the
decomposition of the multilevel electron spin system into a set of noninteracting two level
systems, an approximation that is valid when the dispersed EPR spectral width is large …
以上显示的是最相近的搜索结果。 查看全部搜索结果