To precisely obtain the polarimetric scattering matrix (PSM) of moving target, a measurement model for the simultaneous fully polarimetric radar is formulated. The calibration errors and isolation of the transmitted waveforms are considered. To address the decline in performance of the traditional PSM estimation methods when the target moves, a novel method with measurement selection is proposed. Numerical experiments are conducted to demonstrate and validate the superiority of the proposed method, especially for the PSM estimation of the target with non-uniform motion.