The heat treatment of stone to enhance flaking attributes was an important advance in the adaptive toolkit of humans and a major step in pyrotechnology. The earliest evidence for this is the heat treatment of silcrete ~164 ka at the Middle Stone Age site, Pinnacle Point 13B in South Africa. Heating stone prior to knapping alters the physical and chemical composition of the stone. This study investigates whether surface roughness, as measured by a 3D microscope, can be used as a proxy to identify the presence of heat treatment in the archaeological record. We record values for multiple surface texture parameters on a sample of experimentally created stone tools from paired heat-treated and unheated silcrete nodules. A Bayesian probability model, trained on the experimental sample, was then used to evaluate the probability individual samples have undergone heat treatment. Furthermore, we tested whether an industrial silicon compound can be used to record and preserve surface roughness for analysis. This research provides a novel, probabilistic, and non-invasive technique for identifying heat treatment from three sources near Pinnacle Point.