Activating multistep charge-transfer processes in fullerene− subphthalocyanine− ferrocene molecular hybrids as a function of π− π orbital overlap
D González-Rodríguez, E Carbonell… - Journal of the …, 2010 - ACS Publications
We have synthesized two different fullerene− subphthalocyanine− ferrocene conjugates.
The molecules were designed so that the ferrocene unit is linked at the subphthalocyanine
axial position through a phenoxy spacer while the C60 is rigidly held close to the concave
face of the macrocycle via a 3-fold C 3-symmetrical anchoring. The Bingel trisaddition
reaction leading to the final products proceeded with very high regioselectivities and full
diastereoselectivity. The only difference between both systems is the length of the triple …
The molecules were designed so that the ferrocene unit is linked at the subphthalocyanine
axial position through a phenoxy spacer while the C60 is rigidly held close to the concave
face of the macrocycle via a 3-fold C 3-symmetrical anchoring. The Bingel trisaddition
reaction leading to the final products proceeded with very high regioselectivities and full
diastereoselectivity. The only difference between both systems is the length of the triple …
[引用][C] Activating Multistep Charge-Transfer Processes in Fullerene-Subphthalocyanine-Ferrocene Molecular Hybrids as a Function of π-π Orbital Overlap
DM Guldi - ECS Meeting Abstracts, 2011 - iopscience.iop.org
… We have synthesized two different C60 fullerene-subphthalocyanine-ferrocene covalent triad
hybrids. The molecules were designed so that the ferrocene unit is linked at the subphthalocyanine
axial position through a phenoxy spacer while the C60 is rigidly held close to the concave face
of the macrocycle via a threefold C3-symmetrical anchoring. The Bingel trisaddition reaction
leading to the final products was found to proceed with very high regioselectivities and full
diastereoselectivity. The only difference between both systems is the length of the triple …
hybrids. The molecules were designed so that the ferrocene unit is linked at the subphthalocyanine
axial position through a phenoxy spacer while the C60 is rigidly held close to the concave face
of the macrocycle via a threefold C3-symmetrical anchoring. The Bingel trisaddition reaction
leading to the final products was found to proceed with very high regioselectivities and full
diastereoselectivity. The only difference between both systems is the length of the triple …
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