Al3+ solvation in solutions of aluminum nitrate in a protic ionic liquid: Nuclear magnetic resonance verification of the solvation shell composition
VV Matveev, A Ievlev, M Šoltésová… - Magnetic …, 2022 - Wiley Online Library
VV Matveev, A Ievlev, M Šoltésová, H Štěpánková, E Lähderanta, LM Varela
Magnetic Resonance in Chemistry, 2022•Wiley Online LibraryThe closest environment of Al3+ cations was analyzed in detail in solutions of aluminum
nitrate in the prototypical protic ionic liquid ethyl ammonium nitrate (EAN) using 1H and 14N
nuclear magnetic resonance (NMR) spectra. For Al (NO3) 3–EAN mixtures with different
water content, a quantitative analysis of the integral intensities of the 1H and 14N signals
was carried out and the composition of the first solvation shell of the aluminum cation was
refined.
nitrate in the prototypical protic ionic liquid ethyl ammonium nitrate (EAN) using 1H and 14N
nuclear magnetic resonance (NMR) spectra. For Al (NO3) 3–EAN mixtures with different
water content, a quantitative analysis of the integral intensities of the 1H and 14N signals
was carried out and the composition of the first solvation shell of the aluminum cation was
refined.
Abstract
The closest environment of Al3+ cations was analyzed in detail in solutions of aluminum nitrate in the prototypical protic ionic liquid ethyl ammonium nitrate (EAN) using 1H and 14N nuclear magnetic resonance (NMR) spectra. For Al (NO3)3–EAN mixtures with different water content, a quantitative analysis of the integral intensities of the 1H and 14N signals was carried out and the composition of the first solvation shell of the aluminum cation was refined.
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