Alkaline–Acid Zn–H2O Fuel Cell for the Simultaneous Generation of Hydrogen and Electricity

P Cai, Y Li, G Wang, Z Wen - Angewandte Chemie, 2018 - Wiley Online Library
P Cai, Y Li, G Wang, Z Wen
Angewandte Chemie, 2018Wiley Online Library
An alkaline–acid Zn–H2O fuel cell is proposed for the simultaneous generation of electricity
with an open circuit voltage of about 1.25 V and production of H2 with almost 100% Faradic
efficiency. We demonstrate that, as a result of harvesting energy from both electrochemical
neutralization and electrochemical Zn oxidation, the as‐developed hybrid cell can deliver a
power density of up to 80 mW cm− 2 and an energy density of 934 Wh kg− 1 and maintain
long‐term stability for H2 production with an output voltage of 1.16 V at a current density of …
Abstract
An alkaline–acid Zn–H2O fuel cell is proposed for the simultaneous generation of electricity with an open circuit voltage of about 1.25 V and production of H2 with almost 100 % Faradic efficiency. We demonstrate that, as a result of harvesting energy from both electrochemical neutralization and electrochemical Zn oxidation, the as‐developed hybrid cell can deliver a power density of up to 80 mW cm−2 and an energy density of 934 Wh kg−1 and maintain long‐term stability for H2 production with an output voltage of 1.16 V at a current density of 10 mA cm−2.
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