Bioinspired terpene synthesis: a radical approach

J Justicia, LA de Cienfuegos, AG Campana… - Chemical Society …, 2011 - pubs.rsc.org
Chemical Society Reviews, 2011pubs.rsc.org
This tutorial review highlights the development of radical-based bioinspired synthesis of
terpenes from the initial proposal to the development of modern catalytic methods for
performing such processes. The power of the radical approach is demonstrated by the
straightforward syntheses of many natural products from readily available starting materials.
The efficiency of these processes nicely complements the described cationic polyolefin
cyclisations and even suggests that modern radical methods provide means to improve …
This tutorial review highlights the development of radical-based bioinspired synthesis of terpenes from the initial proposal to the development of modern catalytic methods for performing such processes. The power of the radical approach is demonstrated by the straightforward syntheses of many natural products from readily available starting materials. The efficiency of these processes nicely complements the described cationic polyolefin cyclisations and even suggests that modern radical methods provide means to improve upon nature's synthetic pathways.
The Royal Society of Chemistry
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